, Volume 26, Issue 1, pp 399–407 | Cite as

Copolymer of Di (methacryloyloxymethyl) naphthalene and divinylbenzene as a column packing for high-performance liquid chromatography

  • B. Gawdzik
  • J. Gawdzik
  • U. Czerwińska-Bil


A new porous polyaromatic ester packing was synthetized for high performance liquid chromatography. The relationship between retention and chain length of the members of homologous series of alkylbenzenes, N-alkylanilines, alkylarylethers, alkylbenzoates and alkylarylketones on this new stationary phase using different eluents was investigated. Using the alkylarylketone scale the retention indices of the homologues and test compounds were calculated. The results were compared with those obtained for poly (styrene-divinylbenzene) polymers. For both types of packing the first members of each homologous series gave non-linear behaviour. The methylene group index increments are different for the studied homologous series; thus there is no simple additivity of the retention indices. The efficiency of the porous polymeric columns is a function of the capacity factor of the solute and the organic component of the eluent.

Key Words

Reversed-phase HPLC Porous polyaromatic ester packing LC retention indices/alkylarylketone scale Homologous series 


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  1. [1]
    K. K. Unger, “Porous Silica”, Elsevier, Amsterdam, 1979.Google Scholar
  2. [2]
    H. W. Stuurman, J. Köhler, S. O. Jansson, A. Litzén, Chromatographia23, 341 (1987).Google Scholar
  3. [3]
    D. J. Pietrzyk, Chi-Hong Chu, Anal. Chem.49, 757 (1977).Google Scholar
  4. [4]
    M. Uchida, T. Tanimura, J. Chromatogr.138, 17 (1977).Google Scholar
  5. [5]
    A. Nakae, K. Kinihiro, G. Muto, J. Chromatogr.134, 459 (1977).Google Scholar
  6. [6]
    M. Tanaka, H. Goodell, B. L. Karger, J. Chromatogr.158, 233 (1978).Google Scholar
  7. [7]
    Z. Iskandarani, D. J. Pietrzyk, Anal. Chem.53, 489 (1981).Google Scholar
  8. [8]
    D. P. Lee, J. Chromatogr. Sci.20, 203 (1982).Google Scholar
  9. [9]
    R. G. Baum, R. Saetre, F. F. Cantwell, Anal. Chem.52, 15 (1980).Google Scholar
  10. [10]
    K. Aramaki, T. Hanai, H. F. Walton, Anal. Chem.52, 1965 (1980).Google Scholar
  11. [11]
    Z. Iskandarani, D. J. Pietrzyk, Anal. Chrm.54, 1065 (1982).Google Scholar
  12. [12]
    A. Sugii, N. Ogawa, K. Harada, I. Sato, J. Chromatogr.294, 185 (1984).Google Scholar
  13. [13]
    J. R. Benson, D. J. Woo, J. Chromatogr. Sci.22, 386 (1984).Google Scholar
  14. [14]
    I. O. Kibwage, E. Roets, J. Hoogmartens, H. Vanderhaeghe, J. Chromatogr.330, 275 (1985).Google Scholar
  15. [15]
    K. Wolfs, E. Roets, J. Hoogmartens, H. Vanderhaeghe, J. Chromatogr.358, 444 (1986).Google Scholar
  16. [16]
    K. A. Tweeten, T. N. Tweeten, J. Chromatogr,359, 111 (1986).Google Scholar
  17. [17]
    D. P. Lee, J. H. Kindsvater, Anal. Chem.52, 2425 (1980).Google Scholar
  18. [18]
    F. Nevejans, M. Verzele, J. Chromatogr.406, 325 (1987).Google Scholar
  19. [19]
    A. Patrykiejew, B. Gawdzik, J. Chromatogr.365, 251 (1986).Google Scholar
  20. [20]
    A. Patrykiejew, B. Gawdzik, J. Chromatogr.369, 182 (1986).Google Scholar
  21. [21]
    B. Gawdzik, A. Patrykiejew, J. Chromatogr. (in press).Google Scholar
  22. [22]
    J. Gawdzik, B. Gawdzik, U. Czerwińska-Bil, Chromatographia25, 504 (1988).Google Scholar
  23. [23]
    T. Matynia, B. Gawdzik, Angew. Makromol. Chem.,147, 123 (1987).Google Scholar
  24. [24]
    B. Gawdzik, T. Matynia, Angew. Makromol. Chem.152, 33 (1987).Google Scholar
  25. [25]
    B. Gawdzik, T. Matynia, React. Polym.5, 197 (1987).Google Scholar
  26. [26]
    R. M. Smith, J. Chromatogr.236, 313 (1982).Google Scholar
  27. [27]
    R. M. Smith, J. Chromatogr.236, 321 (1982).Google Scholar
  28. [28]
    R. M. Smith, Anal. Chem.56, 256 (1984).Google Scholar
  29. [29]
    R. M. Smith, J. Chromatogr.291, 372 (1984).Google Scholar
  30. [30]
    R. M. Smith, G. A. Murilla, C. M. Burr, J. Chromatogr.388, 37 (1987).Google Scholar
  31. [31]
    R. M. Smith, D. R. Garside, J. Chromatogr.407, 19 (1987).Google Scholar
  32. [32]
    J. Ugelstad, P. C. Mørk, K. H. Kaggerud, T. Ellingsen, A. Berge, Adv. Colloid Interface Sci.13, 101 (1980).Google Scholar
  33. [33]
    J. Ugelstad, P. C. Mørk, A. Berge, T. Ellingsen, A. A. Khan, “Emulsion Polymerization” Pirma J. Ed., Academic Press, New York, 1982; Chapter 11.Google Scholar
  34. [34]
    G. E. Berendsen, R. Regouw, L. de Galan, Anal. Chem.51, 1091 (1979).Google Scholar
  35. [35]
    S. Coppi, G. Blo, A. Betti, J. Chromatogr.388, 135 (1987).Google Scholar
  36. [36]
    A. M. Krsludovic, H. Colin, G. Guiochon, Anal. Chem.54, 2438 (1982).Google Scholar
  37. [37]
    G. E. Berendsen, Ph. D. Thesis, University of Delft, 1980, p. 87.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1988

Authors and Affiliations

  • B. Gawdzik
    • 1
  • J. Gawdzik
    • 1
  • U. Czerwińska-Bil
    • 1
  1. 1.Institute of ChemistryMaria Curie-Sklodowska UniversityLublinPoland

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