Chromatographia

, Volume 26, Issue 1, pp 399–407 | Cite as

Copolymer of Di (methacryloyloxymethyl) naphthalene and divinylbenzene as a column packing for high-performance liquid chromatography

  • B. Gawdzik
  • J. Gawdzik
  • U. Czerwińska-Bil
Article

Summary

A new porous polyaromatic ester packing was synthetized for high performance liquid chromatography. The relationship between retention and chain length of the members of homologous series of alkylbenzenes, N-alkylanilines, alkylarylethers, alkylbenzoates and alkylarylketones on this new stationary phase using different eluents was investigated. Using the alkylarylketone scale the retention indices of the homologues and test compounds were calculated. The results were compared with those obtained for poly (styrene-divinylbenzene) polymers. For both types of packing the first members of each homologous series gave non-linear behaviour. The methylene group index increments are different for the studied homologous series; thus there is no simple additivity of the retention indices. The efficiency of the porous polymeric columns is a function of the capacity factor of the solute and the organic component of the eluent.

Key Words

Reversed-phase HPLC Porous polyaromatic ester packing LC retention indices/alkylarylketone scale Homologous series 

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Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1988

Authors and Affiliations

  • B. Gawdzik
    • 1
  • J. Gawdzik
    • 1
  • U. Czerwińska-Bil
    • 1
  1. 1.Institute of ChemistryMaria Curie-Sklodowska UniversityLublinPoland

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