Summary
Thermodynamic characteristics determined from retention data measured under isothermal conditions were used for the calculation of retention indices of a number of model compound. The minimum retention index difference required for the identification of two adijacent compounds as well the temperature dependency of retention index are discussed. The possibility of alculating thermodynamic characteristics from retention indices published in the literature was also investigated.
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Dedicated to Professro J. F. K. Huber on the occasion of his 60th birthday.
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Podmaniczky, L., Szepesy, L., Lakszner, K. et al. Relationship between thermodynamic characteristics and isothermal retention indices. Chromatographia 20, 623–628 (1985). https://doi.org/10.1007/BF02263223
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DOI: https://doi.org/10.1007/BF02263223