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Determination of thermodynamic characteristics from retention data in GC

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Summary

Retention data have been measured for model substances of different polarities under isothermal conditions at several temperatures using capillary columns coated with Carbowax-20M and SP-2100 stationary phases. By using the k′ capacity ratios obtained for various temperatures the thermodynamic characteristics of the partition process were determined. For homologous series linear relationships can be established between thermodynamic characteristics and carbon number. Thermodynamic characteristics can be used both to compare and evaluate column quality and to predict retention indices for different temperatures and linear programmed temperature conditions.

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References

  1. A. B. Littlewood, C. S. G. Phillips, D. T. Price, J. Chem. Soc. 1955, 1480.

  2. H. Purnell, Gas Chromatography, J. Wiley & Sons, New York, 1962.

    Google Scholar 

  3. A. B. Littlewood, Gas Chromatography, 2nd ed., Academic Press, New York-London, 1970.

    Google Scholar 

  4. L. S. Ettre, Basic relationships of gas chromatography, The Perkin-Elmer Corp. Nerwalk. Conn. 1977, p. 21.

    Google Scholar 

  5. G. Blu, L. Jacob, G. Guiochon, J. Chromatogr.50, 1 (1970).

    Google Scholar 

  6. R. V. Golovnya, Yu. N. Arsenyev, Chromatographia,4, 250 (1971).

    Google Scholar 

  7. R. V. Golovnya, Chromatographia,12, 533 (1979).

    Google Scholar 

  8. R. V. Golovnya, I. L. Zhuravleva, Chromatographia,6, 508 (1973).

    Google Scholar 

  9. R. V. Golovnya, D. N. Grigoryeva, Chromatographia,17, 613 (1983).

    Google Scholar 

  10. R. V. Golovnya, D. N. Grigoryeva, HRC & CC6, 269 (1983).

    Google Scholar 

  11. A. S. Leshchiner, S. A. Voitkevich, B. A. Rudenko, S. S. Yufit, Chromatographia,6, 314 (1973).

    Google Scholar 

  12. R. W. Dwyer, J. Chromatog. Sci.15, 450 (1977).

    Google Scholar 

  13. L. Podmaniczky, L. Szepesy, K. Lakszner, G. Schomburg, Chromatographia,10, 623 (1985).

    Google Scholar 

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Authors and Affiliations

  1. Dept. of Chemical Technology, Technical University of Budapest, 1521, Budapest, Hungary

    L. Podmaniczky, L. Szepesy & K. Lakszner

  2. MPI für Kohlenforschung, Kaiser-Wilhelm-Platz 1, 4330, Mülheim a. d. Ruhr, FRG

    G. Schomburg

Authors
  1. L. Podmaniczky
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  2. L. Szepesy
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  3. K. Lakszner
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  4. G. Schomburg
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Additional information

Dedicated to Professor J. F. K. Huber on the occasion of his 60th birthday.

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Podmaniczky, L., Szepesy, L., Lakszner, K. et al. Determination of thermodynamic characteristics from retention data in GC. Chromatographia 20, 591–595 (1985). https://doi.org/10.1007/BF02263217

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  • DOI: https://doi.org/10.1007/BF02263217

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