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A thermodynamic criterion for the identification of the functional group of aliphatic compounds by gas chromatography

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Summary

A thermodynamic criterion, ΔQ, is suggested which permits to estimate the difference in the functional group energy of interactions for two different stationary phases. The linear dependence of ΔQ on the homolog number m of any series Rm X can be used as the thermodynamic criterion for the identification of substances by GC analysis.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organo-Element Compounds of the USSR Academy of Sciences, Vavilova str. 28, Moscow, USSR

    R. V. Golovnya & D. N. Grigoryeva

Authors
  1. R. V. Golovnya
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  2. D. N. Grigoryeva
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Golovnya, R.V., Grigoryeva, D.N. A thermodynamic criterion for the identification of the functional group of aliphatic compounds by gas chromatography. Chromatographia 18, 449–455 (1984). https://doi.org/10.1007/BF02262976

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  • DOI: https://doi.org/10.1007/BF02262976

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