Skip to main content
SpringerLink
Log in

Gas chromatographic analysis of C1–C4 nitroparaffins. Separation and identification

  • Originals
  • Published:
Chromatographia Aims and scope Submit manuscript

Summary

The separation of C1–C4 nitroparaffins on SE-30, PEGA and Porapak R stationary phases was investigated. The nitroparaffin mixture was obtained from a real technological process. The best separation was achieved on Porapak R at 190°C. The fact that each peak obtained from this column corresponded to a single compound was checked by utilizing the linear relationship between the peak widths and the adjusted retention times (t′ R ). Peak identification was carried out using the chromatographic data only, with help of plots of log t′ R vs. carbon number and log t′ R vs. boiling point; some of the results were also confirmed with comparing the retention times with those of pure substances and IR investigation of the collected chromatographic fraction.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R. M. Bethea andF. S. Adams, J. Chromatogr.8, 532 (1962).

    Article  Google Scholar 

  2. R. M. Bethea andT. D. Wheelock, Anal. Chem.31, 1834 (1959).

    Article  Google Scholar 

  3. R. M. Bethea andF. S. Adams, J. Chromatogr.10, 1 (1963).

    Article  PubMed  Google Scholar 

  4. D. L. Frear andG. Bumet, J. Chromatogr.19, 17 (1965).

    Article  PubMed  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Organic-Chemical Technology, Institute of Chemical Technology, Burgas, Bulgaria

    S. Boneva, I. Mladenov & P. Toromanova

  2. Chemical Pharmaceutical Institute, Sofia, Bulgaria

    N. Dimov

Authors
  1. S. Boneva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. I. Mladenov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. Toromanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. N. Dimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Boneva, S., Mladenov, I., Toromanova, P. et al. Gas chromatographic analysis of C1–C4 nitroparaffins. Separation and identification. Chromatographia 11, 26–29 (1978). https://doi.org/10.1007/BF02262950

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02262950

Keywords

Search

Navigation