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Correlation between the retention data of polycyclic aromatic hydrocarbons and several descriptors in reversed-phase HPLC

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Summary

The separation of polycyclic aromatic hydrocarbons (PAH) on various reversed-phase columns (phenyl, ethyl, octyl and octadecyl) have been compared. The correlations between the logarithm of capacity factor (log k′) and several descriptors, which show the molecular size, shape and physical property of a solute, were determined. The results indicated the high possibility to predict the retention of PAH in reversed-phase high performance liquid chromatography.

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Authors and Affiliations

  1. School of Materials Science, Toyohashi University of Technology, 440, Toyohashi, Japan

    K. Jinno & K. Kawasaki

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  1. K. Jinno
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  2. K. Kawasaki
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Jinno, K., Kawasaki, K. Correlation between the retention data of polycyclic aromatic hydrocarbons and several descriptors in reversed-phase HPLC. Chromatographia 17, 445–449 (1983). https://doi.org/10.1007/BF02262927

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