Summary
Two liquid chromatographic methods are described for the separation and determination of components in the production of acrylamide by the catalytic hydration of acrylonitrile. The first of these provides a rapid technique by which concentrations and conversion can be directly determined for process control applications, whilst the second represents a more rigorous separation of all possible impurities for quality control purposes.
Similar content being viewed by others
References
D. C. MacWilliams, inM. Grayson ed., Kirk-Othmer Encyclopaedia of Chemical Technology, 3rd ed.,1, 298–310, Wiley Interscience (1978).
The Dow Chemical Company, Chemical Engineering80, (27), 68 (1973).
E. Otsuka, T. Takahashi, N. Hashimoto andF. Matsuda, Chem. Eco. Eng. Rev.1 (4), 29 (1975).
F. Matsuda, Chem. Tech.7, 306 (1977).
N. C. Deno, T. Edwards andC. Perrizolo, J. Am. Chem. Soc.79, 2108 (1957).
E. P. Grigoryan, G. F. Vytnov, R. N. Rodyukova andN. Ipatova, Zh. Prikl. Khim.49 (9), 2043 (1976).
J. Zahora, M. Bielkova andV. Kalab, Chem. Prum.20 (11), 534 (1970).
A. P. Terentiev, M. M. Buzlanova andS. I. Obtemperanskaya, Zh. Anal. Khim.14, 596 (1959);A. P. Terentiev, M. M. Buzlanova andS. I. Obtemperanskaya, Zh. Anal. Chem.175, 385 (1960).
N. V. Norris, inF. D. Snell andC. L. Hilton ed., Encyclopaedia of Industrial Chemical Analysis4, 160–168 and 368–381, Wiley Interscience (1967).
E. R. Husser, R. H. Stehl, D. R. Price andR. A. DeLap, Anal. Chem.49 (1), 154 (1977).
G. Schmoetzer, Chromatographia4 (9), 391 (1971).
B. T. Croll, Analyst96 (1138), 67 (1971).
B. T. Croll andG. M. Simkins, Analyst97 (1153), 261 (1972).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Onuoha, N.I., Chaplin, R.P. & Wainwright, M.S. High-performance liquid chromatographic analyses for use in the acrylamide synthesis process. Chromatographia 12, 709–712 (1979). https://doi.org/10.1007/BF02262447
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02262447