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A study of the activity of chemical groups on carbonaceous and model surfaces by infinite dilution chromatography

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Summary

Surface properties of activated carbons and carbon fibers subjected to oxidation processes are investigated by means of inverse gas chromatography (IGC). A general correlation between surface density of acidic groups and the empirical parameter επ related to electron acceptor interactions is established. Model adsorbents based on benzene derivatives with known numbers of functional groups are also studied by IGC to examine the effect of surface geometry in relationship to the επ results from the carbons.

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  1. J. Jagiełło

    Present address: Institute of Energochemistry of Coal and Physicochemistry of Sorbents, University of Mining and Metallurgy, 30-059, Kraków, Poland

Authors and Affiliations

  1. Department of Chemical Engineering and Materials Science, Syracuse University, 13244-1190, Syracuse, NY, USA

    T. J. Bandosz & J. A. Schwarz

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  1. J. Jagiełło
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  2. T. J. Bandosz
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  3. J. A. Schwarz
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Jagiełło, J., Bandosz, T.J. & Schwarz, J.A. A study of the activity of chemical groups on carbonaceous and model surfaces by infinite dilution chromatography. Chromatographia 33, 441–444 (1992). https://doi.org/10.1007/BF02262324

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  • DOI: https://doi.org/10.1007/BF02262324

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