Advertisement

Chromatographia

, Volume 29, Issue 9–10, pp 419–428 | Cite as

Liquid chromatography with charge transfer complexation

  • J. M. Roussel
  • A. M. Siouffi
  • M. Julliard
  • M. Chanon
Originals

Summary

The paper describes the retention changes observed when an organic acceptor is added to the mobile phase of a liquid chromatography system. The capacity factor decrease depends on the donor character of the solute. Correlations with ionization potentials, HOMO energies and half wave oxidation potentials demonstrate the role of the organic acceptor. According monstrate the role of the organic acceptor. According to the chromatographic properties of the acceptor which is either unretained (TCNE) or slightly retained (TNF) different retention mechanisms are proposed.

Key Words

Column liquid chromatography Acceptor-Donor complexes Selectivity enhancement Physical properties/retention correlation 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. [1]
    R. S. Mulliken, W. W. Person, Molecular Complexes, Wiley Interscience, N. Y. 1969.Google Scholar
  2. [2]
    R. Foster, Molecular Complexes Elek Sciences, London 1974.Google Scholar
  3. [3]
    M. A. Slifkin, Charge Transfer Interactions of Biomolecules, Academic Press, London 1971.Google Scholar
  4. [4]
    G. Jones, in “Photoinduced Electron Transfer”,M. A. Fox andM. Chanon ed., Elsevier, Amsterdam 1988, Chapter 7 in part A.Google Scholar
  5. [5]
    Y. B. Yang, M. Verzele, J. Chromatogr.387, 197 (1987).Google Scholar
  6. [6]
    J. Porath, J. Chromatogr.159, 13 (1978).Google Scholar
  7. [7]
    L. Nondek, J. Chromatogr.373, 61 (1986).Google Scholar
  8. [8]
    G. Felix, C. Bertrand, J. Chromatogr.319, 432 (1985).Google Scholar
  9. [9]
    T. H. Mourey, S. Siggia, Anal. Chem.51, 763 (1979).Google Scholar
  10. [10]
    C. H. Lochmuller, S. F. Marshall, D. R. Wilder, Anal. Chem.52, 19 (1980).Google Scholar
  11. [11]
    W. Holstein, Chromatographia14, 468 (1981).Google Scholar
  12. [12]
    G. Schomburg, K. Zegarsky, J. Chromatogr.114, 174 (1985).Google Scholar
  13. [13]
    B. Vonach, G. Schomburg, J. Chromatogr.149, 417 (1978).Google Scholar
  14. [14]
    P. L. Phelan, J. R. Miller, J. Chrom. Sci.19, 13 (1981).Google Scholar
  15. [15]
    V. Walters, N. V. Raghavan, J. Chromatogr.176, 470 (1979).Google Scholar
  16. [16]
    Cs. Horwath, W. Melander, A. Nahum, Advances in Chromatography,A. Zlatkis ed., 1979, p. 387.Google Scholar
  17. [17]
    S. Levin, E. Grushka, Anal. Chem.58, 1602 (1986).Google Scholar
  18. [18]
    M. Julliard, A. Galadi, M. Chanon, J. Photochem. and Photobiol. 1990 (in press).Google Scholar
  19. [19]
    B. L. Karger, M. Martini, H. Loheac, G. Guiochon, Anal. Chem.45, 496 (1973).Google Scholar
  20. [20]
    G. Briegleb, Molekülverbindungen und Koordinationsverbindungen in Einzeldarstellungen-Elektronen Donator-Akzeptor-Komplexe, Berlin 1961.Google Scholar
  21. [21]
    A. M. Simon, Ph. D thesis, Marseille, France, 1984.Google Scholar
  22. [22]
    R. J. Laub, R. L. Pecsok, J. Chromatogr.,113, 47 (1975).Google Scholar
  23. [23]
    T. Koopman, Physica.,1 104 (1933).Google Scholar
  24. [24]
    K. O. Borg, G. Schill, Acta Pharm. Succica.,5, 323 1968.Google Scholar
  25. [25]
    J. H. Knox, G. R. Laird, J. Chromatogr.,122, 17 (1976).Google Scholar
  26. [26]
    W. Melander, Cs. Horwath, Ion Pair Chromatography,M. T. W. Hearn ed., Marcel Dekker, N. Y., 1985, p. 27–75.Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1990

Authors and Affiliations

  • J. M. Roussel
    • 1
  • A. M. Siouffi
    • 1
  • M. Julliard
    • 2
  • M. Chanon
    • 2
  1. 1.Laboratoire de Génie Chimique et Chimie AppliquéeURA CNRS 126; Faculté des Sciences et Techniques de Saint Jérôme Université d' Aix-Marseille IIIMarseille Cedex 13France
  2. 2.Laboratoire de Chimie Moléculaire et de Pétroléochimie-URA CNRS 126; Faculté des Sciences et Techniques de Saint JérômeUniversité d' Aix-Marseille IIIMarseille Cedex 13France

Personalised recommendations