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Dicyclopentadiene dissociation in a chromatographic reactor. Effect of the liquid phase polarity on the reaction rate

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Summary

The gas chromatographic reactor technique was used to study the kinetics of dicyclopentadiene dissociation in several liquid phases (Versamid 900, neopentyl glycol sebacate, Triton X-305, Carbowax 6000, ethylene glycol phthalate and diethylene glycol succinate). Reaction rates and Arrhenius parameters are reported in the temperature range of 170–200°C. Kinetic data for the lower polarity liquid phases are in good agreement with literature values for liquid phases of the same nature reported previously. Reaction rates are higher when polar liquid phases are used. This behavior can be explained as a result of side reactions which lead to high molecular weight compounds which can be observed in the reaction chromatogram.

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References

  1. E. Gil-Av, Y. Herzberg-Minzly, Proc. Chem. Soc.316 (1961).

  2. S. H. Langer, J. E. Patton, Chemical reactor applications of the gas chromatographic column, inJ. H. Purnell (ed.), “New Developments in Gas Chromatography”, Wiley, New York, pp. 293–373 (1973).

    Google Scholar 

  3. S. H. Langer, J. E. Patton, J. Phys. Chem.76, 2159 (1972).

    Google Scholar 

  4. S. Z. Roginskii, M. I. Yanovskii, G. A. Gaziev, Dokl. Akad. Nauk., SSSR,140, 1185 (1961).

    Google Scholar 

  5. D. Schweich, J. Villermaux, Ind. Eng. Chem. Fund.17, 1 (1978).

    Google Scholar 

  6. V. G. Berezquin, Russ. Chem. Rev.37, 576 (1968).

    Google Scholar 

  7. S. H. Langer, J. Y. Yurchak, J. E. Patton, Ind. Eng. Chem.61, 10 (1969).

    Google Scholar 

  8. J. Villermaux, “The Chromatographic Reactor”, in “Percolation Processes: Theory and Application”, (Eds.Rodrigues, A. E., Tondeur, D.), Sythoff and Noordhoff, The Netherlands, pp. 539–588 (1981).

    Google Scholar 

  9. N. C. Saha, D. S. Mathur, J. Chromatogr.81, 207 (1973).

    Google Scholar 

  10. D. Schweich, J. Villermaux, Ind. Eng. Chem. Fund.21, 47 (1982).

    Google Scholar 

  11. M. Bravo, Ph. D. Thesis, University of Oviedo, Oviedo (1975).

  12. J. Coca, G. Adrio, S. H. Langer, Chem. Eng. Sci.43, 2007 (1988).

    Google Scholar 

  13. J. Coca, M. Bravo, S. H. Langer, React. Kinet. Catal. Lett.27, 1 (1985).

    Google Scholar 

  14. W. C. Herndon, C. R. Grayson, J. M. Manion, J. Org. Chem.32, 526 (1967).

    Google Scholar 

  15. W. O. MacReynolds, J. of Chromatogr. Sci.8, 686 (1970).

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Oviedo, E-33071, Oviedo, Spain

    J. Coca, M. Bravo, E. Abascal & G. Adrio

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  1. J. Coca
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  2. M. Bravo
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  3. E. Abascal
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  4. G. Adrio
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Coca, J., Bravo, M., Abascal, E. et al. Dicyclopentadiene dissociation in a chromatographic reactor. Effect of the liquid phase polarity on the reaction rate. Chromatographia 28, 300–302 (1989). https://doi.org/10.1007/BF02260779

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  • DOI: https://doi.org/10.1007/BF02260779

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