Summary
A significant correlation has been found between the retention indices of polycyclic aromatic hydrocarbons on non-polar stationary phases and the average molecular polarizabilities of the molecules separated on these phases. Equations have been derived for the determination of the average molecular polarizabilities, directly from the retention indices.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
M. Gassiot-Matas andG. Firpo-Pamies, J. Chromatogr.187, 1 (1980).
R. V. Golovnya, Chromatographia12, 533 (1979).
J. Grzybowski, H. Lamparczyk, A. Nasal andA. Radecki, J. Chromatogr.196, 217 (1980).
R. Kaliszan, J. Chromatogr., in press.
R. Kaliszan andH. Lamparczyk, J. Chromatogr. Sci.16, 246 (1978).
A. Vogel, J. Chem. Soc. 1948, 1833.
K. G. Denbigh, Trans. Faraday Soc.36, 938 (1940).
K. J. Miller andJ. A. Savchik, J. Amer. Chem. Soc.101, 7206 (1979).
G. Grimmer andH. Böhnke, J. Ass. Offic. Anal. Chem.58, 725 (1975).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lamparczyk, H., Wilczyńska, D. & Radecki, A. Determination of average molecular polarizabilities of polycyclic aromatic hydrocarbons directly from retention indices. Chromatographia 14, 707–708 (1981). https://doi.org/10.1007/BF02259460
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02259460