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A proposal for the application of ligand-exchange chromatography on thin-layers

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Summary

Thin-layer chromatography has been performed on plates spread with polystyrene-imminodiacetate-exchanger (Chelex 100) bound to the ammonia complexes of different metal ions such as nickel(II), zinc(II), copper(II) and cobalt(III). A ligand-exchange effect was evidenced in the separation of some diamines, α-amino acids and carboxylic acids. The method may be used for the analysis of very dilute solutions and as a useful test of the best operating conditions for column chromatography.

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References

  1. E. Stahl, Dünnschicht Chromatographie, 2nd ed., 534, Springer Berlin 1967.

    Google Scholar 

  2. K. Yasuda, J. Chromatogr.60, 144 (1971).

    Google Scholar 

  3. K. Yasuda, J. Chromatogr.87, 565 (1973).

    Google Scholar 

  4. J. H. P. Tyman, N. Jacobs, J. Chromatogr.54, 83 (1971).

    Google Scholar 

  5. R. S. Prasad, A. S. Gupta, S. Der, J. Chromatogr.92, 450 (1978).

    Google Scholar 

  6. H. F. Walton, J. D. Navratil, Anal. Chem.47, 2243 (1975).

    Google Scholar 

  7. B. Hemmasi, E. Bayer, J. Chromatogr.109, 43 (1975).

    Google Scholar 

  8. R. Bedetti, V. Carunchio, A. Marino, J. Chromatogr.,95, 127 (1974).

    Google Scholar 

  9. H. Rose, Ann. Phys. Chem.20, 155 (1830).

    Google Scholar 

  10. J. P. Bjerrum, J. P. McReynolds, Inorganic Synthesis2, 216 McGraw Inc., New York 1946.

    Google Scholar 

  11. A. Siegel, E. T. Degens, Science151, 1098 (1966).

    Google Scholar 

  12. L. G. Sillen, A. E. Martell, Stability Constants of Metal lon Complexes, Chemical Society, London, 1964.

    Google Scholar 

  13. J. J. Christensen, D. J. Eatongh, R. M. Isatt, Handbook of Metal Ligand Heats and Related Thermodynamic Quantities, New York 1975.

  14. B. Grabaric, I. Filipovic, Croat. Chem. Acta42, 479 (1970).

    Google Scholar 

  15. V. A. Davankov A. V. Semechkin, J. Chromatogr.141, 313 (1977).

    Google Scholar 

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Antonelli, M.L., Marino, A., Messina, A. et al. A proposal for the application of ligand-exchange chromatography on thin-layers. Chromatographia 13, 167–169 (1980). https://doi.org/10.1007/BF02259308

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  • DOI: https://doi.org/10.1007/BF02259308

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