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Contribution of adsorption to retention data in glass capillary gas chromatography part. I. Polar stationary phases

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Summary

The influence of the film thickness of Carbowax 20M coated onto glass surfaces (series of columns with different mode of surface treatment) upon the retention indices of solutes which exhibit tendency to hydrogen bonding has been investigated. Limiting values of Kovats indices, I∞, are calculated for all the columns examined.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemical Technology, Slovak Technical University, 81237, Bratislava, Czechoslovakia

    J. Krupčik, E. Matisová & J. Garaj

  2. Chemical Institute, Comenius University, 81650, Bratislava, Czechoslovakia

    L. Soják

  3. Topchiev's Institute of Petroleum Chemical Synthesis, Academy of Sciences, Lenin Avenue, 117334, Moscow, U.S.S.R.

    V. G. Brezkin

Authors
  1. J. Krupčik
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  2. E. Matisová
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  3. J. Garaj
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  4. L. Soják
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  5. V. G. Brezkin
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Krupčik, J., Matisová, E., Garaj, J. et al. Contribution of adsorption to retention data in glass capillary gas chromatography part. I. Polar stationary phases. Chromatographia 16, 166–168 (1982). https://doi.org/10.1007/BF02258890

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  • DOI: https://doi.org/10.1007/BF02258890

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