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Polyacrylate liquid crystalline stationary phases in supercritical fluid chromatography with carbon dioxide mobile phase

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Summary

New polyacrylate liquid crystalline compounds were coated onto glass or fused-silica capillary columns as stationary phases and applied to supercritical fluid chromatography. These stationary phases, were very stable: no bleeding was observed at 200°C and up to 200kg/cm2 pressures of carbon dioxide mobile phase. The wide working range of the capillary column was extended below the g-n transition temperature. Isomeric compounds such as α- and β-methoxynaphthalene, anthracene and phenanthrene and several phenolic compounds were separated.

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References

  1. E. Klesper, A. H. Corwin, D. A. Turner, J. Org. Chem.,27, 700 (1962).

    Google Scholar 

  2. F. P. Schmitz, E. Klesper, Polymmer Bull.,5, 603 (1981).

    Google Scholar 

  3. Y. Hirata, F. Nakata, J. Chromatogr.,295, 315 (1984).

    Google Scholar 

  4. T. H. Gouw, R. E. Jentoft, Adv. Chromatogr.,13, 1 (1975).

    Google Scholar 

  5. E. Klesper, Angew. Chem. Int. Ed.,17, 738 (1978).

    Google Scholar 

  6. K. Grob, IRC & CC,6, 178 (1983).

    Google Scholar 

  7. M. Novotny, S. R. Springston, P. A. Peaden, J. C. Fjeldsted, M. L. Lee, Anal. Chem.,53, 407A (1981).

    Google Scholar 

  8. J. C. Fjeldsted, M. L. Lee, Anal. Chem.,56, 619A (1984).

    Google Scholar 

  9. F. P. Schmitz, D. Leyendecker, E. Klesper, Ber. Bunsenges. Phys. Chem.,88, 912 (1984).

    Google Scholar 

  10. G. M. Schneider, Angew. Chem. Int. Ed.,17, 716 (1978).

    Google Scholar 

  11. G. M. Schneider, Ber. Bunsenges. Phys. Chem.,88, 841 (1984).

    Google Scholar 

  12. T. Greibrokk, A. L. Blilie, E. J. Johansen, E. Lundanes, Anal. Chem.,56, 2681 (1984).

    Google Scholar 

  13. T. Takeuchi, D. Ishii, J. Chromatogr.,295, 323 (1984).

    Google Scholar 

  14. J. C. Fjeldsted, B. E. Richter, W. P. Jackson, M. L. Lee, J. Chromatogr.,279, 423 (1983).

    Google Scholar 

  15. K. H. Shafer, P. R. Griffiths, Anal. Chem.,55, 1939 (1983).

    Google Scholar 

  16. R. A. Leach, J. M. Harris, Anal. Chem.,56, 2801 (1984).

    Google Scholar 

  17. J. C. Fjeldsted, R. C. Kong, M. L. Lee, J. Chromatogr.,279, 449 (1983).

    Google Scholar 

  18. R. D. Smith, H. R. Udseth, Anal. Chem.,55, 2266 (1983).

    Google Scholar 

  19. R. D. Smith, H. T. Kalinoski, H. R. Udseth, R. W. Wright, Anal. Chem.,56, 2476 (1984).

    Google Scholar 

  20. S. Rokushika, H. Hatano, H. H. Hill, Jr., Manuscript in preparation.

  21. W. L. Zielinski, Jr., K. Johnston, G. M. Muschik, Anal. Chem.,48, 907 (1976).

    Google Scholar 

  22. G. M. Muschik, T. Kelly, W. B. Manning, J. Chromatogr.,202, 75 (1980).

    Google Scholar 

  23. A. Ziolek, Z. Witkiewicz, R. Dabrowski, J. Chromatogr.,299, 159 (1984).

    Google Scholar 

  24. K. P. Naikwadi, S. Rokushika, H. Hatano, M. Ohsima, J. Chromatogr.,331, 69 (1985).

    Google Scholar 

  25. R. C. Kong, M. L. Lee, Y. Tominaga, R. Pratap, M. Iwao, R. N. Castle, Anal. Chem.,54, 1802 (1982).

    Google Scholar 

  26. B. A. Jones, J. S. Bradshaw, M. Nishioka, M. L. Lee, J. Org. Chem.,49, 4947 (1984).

    Google Scholar 

  27. M. A. Apfel, H. Finkelmann, G. M. Janini, R. J. Laub, B.-H. Luhmann, A. Price, W. L. Roberts, T. J. Shaw, C. A. Smith, Anal. Chem.,57, 651 (1985).

    Google Scholar 

  28. K. P. Naikwadi, S. Rokushika, A. L. Jadhav, H. Hatano, M. Ohsima, Makromol. Chem., in press.

  29. S. Rokushika, K. P. Naikwadi, A. L. Jadhav, H. Hatano, HRC & CC,8, 480 (1985).

    Google Scholar 

  30. J. C. Fjeldsted, W. P. Jackson, P. A. Peaden, M. L. Lee, J. Chromatogr. Sci.,21, 222 (1983).

    Google Scholar 

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Author notes

  1. K. P. Naikwadi

    Present address: Department of Chemistry, University of Waterloo, N2L 3G1, Waterloo, Ontario, Canada

Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Kyoto University, Sakyo-ku, 606, Kyoto, Japan

    S. Rokushika, K. P. Naikwadi, A. L. Jadhav & H. Hatano

Authors
  1. S. Rokushika
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  2. K. P. Naikwadi
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  3. A. L. Jadhav
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  4. H. Hatano
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Rokushika, S., Naikwadi, K.P., Jadhav, A.L. et al. Polyacrylate liquid crystalline stationary phases in supercritical fluid chromatography with carbon dioxide mobile phase. Chromatographia 22, 209–212 (1986). https://doi.org/10.1007/BF02257330

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  • DOI: https://doi.org/10.1007/BF02257330

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