Summary
In high pressure gas chromatography efficient columns can be packed by the slurry packing technique. However, polysiloxane stationary phases like OV 101 and OV 3 dissolve in the packing liquids. In order to make them suitable for slurry packing these stationary phases have to be made insoluble. This immobilization is achieved by bonding the stationary phases to the surface by means of a high temperature treatment. Successive layers are applied by recoating and are immobilized by a cross-link reaction. A range of loading percentages from 4 upto 20 by weight could be prepared in this way. On the evaluated columns compounds like butanol and dioxane elute as rather symmetrical peaks with the correct values for the retention index, indicating the absence of adsorption effects. Efficiency is good and bleeding rate is low. The columns could be successfully used in the analysis of turpentines.
Similar content being viewed by others
References
J. F. K. Huber, H. H. Lauer, H. Poppe, J. Chromatogr.,112, 377 (1975).
H. H. Lauer, H. Poppe, J. F. K. Huber, J. Chromatogr.,132, 1 (1977).
Lu Peichang, Zhou Liangmo, Wang Chinghai, Wang Guanghua, Xia Aizu, Xu Fangbao J. Chromatogr.186, 25 (1979).
R. Dandeneau, S. Hawkes, Chromatographia13, 686 (1980).
R. J. Jonker, H. Poppe, J. F. K. Huber, Anal. Chem.54, 2447 (1982).
R. J. Jonker, H. Poppe, J. F. K. Huber, J. Chromatogr.18, 285 (1979).
W. A. Aue, C. R. Hastings, J. Chromatogr.42, 319 (1969).
R. G. Sinclair, E. R. Hinnenkamp, K. A. Boni, D. A. Berry, W. H. Schuller, R. V. Lawrence, J. Chrom. Sci.,9, 126 (1971).
G. Schomburg, A. Deege, J. Köhler, U. Bien-Vogelsang, J. Chromatogr.,282, 27 (1983).
L. Ghaoui, H. Shanfield, A. Zlatkis Chromatographia18, 11 (1984).
L. Blomberg, T. Wännman, J. Chromatogr.168, 81 (1979).
S. R. Lipsky, W. J. McMurray, J. Chromatogr.239, 61 (1982).
B. W. Wright, P. A. Peaden, M. L. Lee, T. J. Stark, J. Chromatogr.248, 17 (1982).
C. Madani, E. M. Chambaz, M. Rigaud, J. Durand, P. Chebroux, J. Chromatogr.126, 161 (1976).
K. Grob, G. Grob, W. Blum, W. Walther, J. Chromatogr.244 197 (1982).
G. Schomburg, H. Husmann, F. Weeke, Chromatographia10, 580 (1977).
G. Schomburg, H. Husmann, H. Borwitzky, Chromatographia12, 651 (1979).
W. Noll, H. Weissbach, Zement, Kalk und Gips9, 476 (1956).
M. Kanazashi, Bull. Electrotechn. Lab.27 175 (1963).
G. Schomburg, H. Husmann, S. Ruthe, M. Herraiz, Chromatographia15, 599 (1982).
J. Buyten, L. Blomberg, K. Markides, T. Wännman, J. Chromatogr.289, 143 (1984).
L. O. Amberg, W. D. Willis, Proc. Int. Rubber Conf. Washington, D. C., Nov. 1959, p. 565.
A. U. Blackham, N. L. Eatough, J. Am. Chem. Soc.,84, 2922 (1962).
W. O. McReynolds, “Gas Chromatography Retention Data”, Preston Technical Abstracts Company, 1966.
K. Grob, G. Grob, J. Chromatogr.213, 211 (1981).
J. F. Zack Jr., E. L. Warrick, G. Knoll, J. Chem. Eng. Data6 (No. 2), 279 (1961).
M. L. Dunham, D. L. Bailey, R. Y. Mixer, Ind. Eng. Chem.49, 1373 (1957).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ghijsen, R.T., Nooitgedacht, F. & Poppe, H. The preparation of immobilized polysiloxane coated on packings materials for high-pressure gas chromatography. Chromatographia 22, 201–208 (1986). https://doi.org/10.1007/BF02257329
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02257329