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Unusual course of the reaction of N-(tosylmethyl)thiourea and N-(azidomethyl)thiourea with sodium enolate of dimedone

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The end product of the reaction of N-(tosylmethyl)thiourea or N-(azidomethyl)thiourea with sodium enolate of dimedone is bis(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)methane (methylenebisdimedone) instead of the expected 8a-hydroxy-7,7-dimethyl-2-thioxoperhydroquinazolin-5-one.

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References

  1. A. D. Shutalev and V. A. Kuksa,Khim. Geterotsikl. Soedin., No. 1, 97 (1995).

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Authors
  1. A. D. Shutalev
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  2. E. A. Kishko
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Additional information

M. V. Lomonosov State Academy of Fine Chemical Technology, Moscow 117571, Russia; Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 70–72, January, 2000.

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Shutalev, A.D., Kishko, E.A. Unusual course of the reaction of N-(tosylmethyl)thiourea and N-(azidomethyl)thiourea with sodium enolate of dimedone. Chem Heterocycl Compd 36, 62–64 (2000). https://doi.org/10.1007/BF02256846

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  • DOI: https://doi.org/10.1007/BF02256846

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