Abstract
Nucleophilic addition of organometallic lithium and magnesium compounds to 1-alkyl-3-(2-quinolyl)quinolinium cations produces a mixture of the corresponding 1′-alkyl-2′-R-1′,2′-dihydro-2,3′-biquinolyls and 1′-alkyl-4′-R-1′,4′-dihydro-2,3′-biquinolyls. The portion of the latter decreases with increasing “hardness” of the organometallic compound.
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References
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Additional information
For No. 5, see [1].
Stavropol State University, Stavropol'355009, Russian Russian Chemical Technology University Moscow 125190 Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 919–923, July, 1999.
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Aksenov, A.V., Nadein, O.N., Moiseev, D.V. et al. Studies of 2,3′-biquinolyl. 6. Regioselectivity of nucleophilic addition of organometallic compounds to 1-aklyl-3-(2-quinolyl)quinolinium halides. Chem Heterocycl Compd 35, 804–808 (1999). https://doi.org/10.1007/BF02252104
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DOI: https://doi.org/10.1007/BF02252104