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Triterpene glycosides ofHedera canariensis IV. Structures of glycosides L-F3, L-G0, and L-Gla from the leaves of Algerian ivy

Abstract

Three minor partially acetylated glycosides have been isolated from the leaves of Algerian ivy, Hedera canariensis Willd. (Araliaceae) — the previously known {3-O-[α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranoside] 28-O-[α-L-rhamnopyranosyl-(1→4)-O-(6-acetyl-β-D-glucopyranosyl)-(1→6)-O-β-D-glucopyranoside}s of oleanolic acid and of hederagenin (ciwujianoside C4 and kizuta saponin K11) and the new 3-O-[α-L-rhamnopyranosyl-(1→2)-α-O-L-arabinopyranoside] 28-O-[α-L-rhamnopyranosyl-(1→4)-O-(6-O-acetyl-β-D-glucopyranosyl)-(1→6)-O-β-D-glucopyranoside of echinocystic acid (glycoside L-G0). The structures of the glycosides isolated have been established on the basis of chemical transformations and1H and13C NMR spectroscopy.

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References

  1. 1.

    V. I. Grishkovets, D. Yu. Sidorov, L. A. Yakovishin, A. S. Shashkov, N. N. Arnautov, and V. Ya. Chirva,Khim. Prir. Soedin., 377 (1996).

  2. 2.

    V. I. Grishkovets, L. A. Yakovishin, I. N. Shchipanova, A. S. Shashkov, and V. Ya. Chirva,Khim. Prir. Soedin., 777 (1998).

  3. 3.

    V. I. Grishkovets, N. V. Tolkacheva, A. S. Shashkov, and V. Ya. Chirva,Khim. Prir. Soedin., 522 (1992).

  4. 4.

    C.-J. Shao, R. Kasai, K. Ohtani, and O. Tanaka,Chem. Pharm. Bull.,38, 1087 (1990).

    Google Scholar 

  5. 5.

    C.-J. Shao, R. Kasai, J.-D. Xu, and O. Tanaka,Chem. Pharm. Bull.,36, 601 (1988).

    Google Scholar 

  6. 6.

    C.-J. Shao, R. Kasai, J.-D. Xu, and O. Tanaka,Chem. Pharm. Bull.,37, 42 (1989).

    Google Scholar 

  7. 7.

    A. S. Shashkov, V. I. Grishkovets, L. A. Yakovishin, I. N. Shchipanova, and V. Ya. Chirva,Khim. Prir. Soedin., 772 (1998).

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Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 81–86, January–February, 1999.

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Yakovishin, L.A., Grishkovets, V.I., Shchipanova, I.N. et al. Triterpene glycosides ofHedera canariensis IV. Structures of glycosides L-F3, L-G0, and L-Gla from the leaves of Algerian ivy. Chem Nat Compd 35, 65–69 (1999). https://doi.org/10.1007/BF02238212

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Keywords

  • Organic Chemistry
  • Glycoside
  • Saponin
  • Chemical Transformation
  • Oleanolic Acid