Summary
Some examples of transesterifications of cardenolidacetates to acetyl-free glycosides with zincacetate are reported. The method is advantageous for the deacetylation of acetates with base-resistant acetyl groups or with special base sensitivity.
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56. Mitteilung über Herzglykoside. 55. Mitt. s. Helv. chim. Acta51, 1317 (1968).
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Abisch, E., Binkert, J. Desazetylierung von Cardenoliden mit der Zinkazetatmethode. Experientia 26, 711–712 (1970). https://doi.org/10.1007/BF02232497
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DOI: https://doi.org/10.1007/BF02232497