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In-line determination of U, Pu and Np in process streams by energy-dispersive X-ray fluorescence analysis (EDXRF)

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Abstract

A γ-ray source of ≈300 keV was used in order to excite the fluorescent K-radiation of the heavy elements which is only weakly absorbed in the walls of metal tubes. Thus, uranium can be determined quantitatively in solutions within tubes in the concentration range form 5 mg/l to 100 g/l. The influences of the energy and the activity of the radiation source, the geometrical arrangement, the thickness of the wall and the wall material have been investigated.

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References

  1. D. C. CAMP, W. D. RUTHER, Determination of actinide process- and product-stream concentrations off-line or at-line by energy dispersive X-ray fluorescence analysis, 3rd Annual Symp. on Safeguards and Nucl. Material Management, ESARDA, Karlsruhe, 6th/8th May 1981.

  2. G. ANDREW, B. L. TAYLOR, C. E. LYON, R. A. SAMBELL, Precise measurement of Pu/U ratio by a new XRF-technique with potential for on-line application, 3rd Annual Symp. on Safeguards and Nuclear Material Management, ESARDA, Karlsruhe, 6th/8th May 1981.

  3. P. MARTINELLI, Systeme d'analyse non destructive de l'Uranium et/ou du Plutonium par fluorescence X excitée au moyen de sources radioactives d'Iridium 192, 3rd Annual Symp. on Safeguards and Nuclear Material Management, ESARDA, Karlsruhe, 6th/8th May 1981. K. H. LIESER, Einführung in die Kernchemie, Verlag Chemie, Weinheim, 1980, 2. Auflage, S. 161 [Formel Nr. 6.19].

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Hofmann, T., Hoffmann, P. & Lieser, K.H. In-line determination of U, Pu and Np in process streams by energy-dispersive X-ray fluorescence analysis (EDXRF). Journal of Radioanalytical and Nuclear Chemistry, Articles 82, 201–204 (1984). https://doi.org/10.1007/BF02227342

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  • DOI: https://doi.org/10.1007/BF02227342

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