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Adsorption characteristics of radiotoxic cesium and iodine from low-level liquid wastes

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Abstract

In order to remove the radiotoxic nuclides, Cs+ and I, from low-level liquid wastes, the adsorption characteristics have been studied using a mixed adsorbent of chabazite zeolite and activated carbon. The equilibrium data of each nuclide were well correlated with the DA equation in the wide range of equilibrium concentrations. The SEM-EDAX analysis provided precise understanding of the adsorption mechanism of each nuclide. A surface diffusion model was applied to estimate the intraparticle mass transfer and provided prediction results acceptable for practical implementation in the liquid waste treatment.

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References

  1. A. A. Moghissi, H. W. Godbee, S. A. Hobart, Radioactive Waste Technology, The ASME, 1986.

  2. M. Benedict, T. H. Pigpord, H. W. Levi, Nuclear Chemical Engineering, McGraw-Hill, Inc., 1981.

  3. R. M. Propst, O. E. Ekechukwu, H. J. Dameron, Pretreatment and Selective Materials for Improved Treatment of PWR Liquid Radioactive Waste, EPRI NP-5786, Electric Power Research Institute, 1988.

  4. B. T. Kim, H. K. Lee, H. Moon, K. J. Lee, Sep. Sci. Technol., 30 (1995) No. 16, 3165.

    Google Scholar 

  5. B. W. Mercer, Jr.,L. L. Ames, Jr., The Adsorption of Cesium and Strontium on Zeolites from Multicomponent Systems, HA-SA-3199, Handford Atomic Products Operations, 1963.

  6. B. W. Merger, Ion Exchange Equilibria of Trace Cesium-137 and Strontium-85 in Multicomponent Systems, BNWL-SA-1173, Battelle Memorial Institute, 1967.

  7. S. Komarneni, R. Roy, Nucl. Chem. Waste Managem., 2 (1981) 259.

    Google Scholar 

  8. T. Kanno, H. Mimura, Ion-Exchange Properties of Zeolites and Their Applicaton to Processing of High-Level Liquid Waste, IAEA-TECDOC-337, IAEA, Vienna, 1985.

    Google Scholar 

  9. K. Mimura, K. Hashimoto, J. Chem. Eng. Japan, 10 (1977)No. 6, 490.

    Google Scholar 

  10. H. Mimura, F. Tachibana, K. Akiba, RECOD '91 (1991) 796.

  11. H. Mimura, K. Akiba, H. Igarashi, J. Nucl. Sci. Technol., 30 (1993) 239.

    Google Scholar 

  12. IAEA, Feasibility of Separation and Utilization of Caesium and Strontium from High Level Liquid Waste, Technical Reports Series No. 356, Vienna, 1993.

  13. J. J. Perona, AIChE J., 39 (1993) No. 10, 1716.

    Google Scholar 

  14. L. L. Kilpatrick, Cesium Removal from Dilute Streams with Epicor Cs-1 Ion Exchange Resin, DPST-85-739, Savanah River Lab., 1985.

  15. S. M. Robinson, J. R. Parrott, Jr., Pilot-Scale Demonstration of Process Wastewater Decontamination Using Chabazite Zeolites, ORNL/TM-10836, Oak Ridge National Lab., 1989.

  16. K. Reaves, J. Kunze, K. Lu, P. C. Bennett, Adsorption of Spent Fuel Storage Pool Contaminants into Metal Surfaces, SAND-90-1683C, 1990.

  17. M. Saleem, M. Afzal, R. Qadeer, J. Hanif, Sep. Sci. Technol., 27 (1992) No. 2, 239.

    Google Scholar 

  18. W. A. Abbasi, M. Streat, Sep. Sci. Technol., 29 (1994) No. 9, 1217.

    Google Scholar 

  19. M. T. Olgun et al., Sep. Sci. Technol., 29 (1994) No. 16, 2161.

    Google Scholar 

  20. C. Tien, Adsorption Calculations and Modeling, Butterworth-Heinemann, London, 1994.

    Google Scholar 

  21. W. Rudzinski, D. H. Everett, Adsorption of Gases on Heterogeneous Surfaces, Academic Press., Inc. New York, 1992.

    Google Scholar 

  22. H. Moon, W. K. Lee, J. Colloid Interface Sci., 96 (1983) 162.

    Google Scholar 

  23. J. S. Mattson, H. B. Mark, Jr., Activated Carbon, Marcel Dekker, Inc., New York, 1971.

    Google Scholar 

  24. P. A. M. Teirlinck, F. W. Petersen, Sep. Sci. Technol., 30 (1995) No. 16, 3129.

    Google Scholar 

  25. S. M. Robinson, W. D. Arnold, C. H. Byers, AIChE J., 40 (1994) No. 12, 2045.

    Google Scholar 

  26. M. Suzuki, Adsorption Engineering, Elsevier Science Publsiehrs, Amsterdam, 1990.

    Google Scholar 

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Song, K.C., Kim, H.D., Lee, H.K. et al. Adsorption characteristics of radiotoxic cesium and iodine from low-level liquid wastes. J Radioanal Nucl Chem 223, 199–205 (1997). https://doi.org/10.1007/BF02223384

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  • DOI: https://doi.org/10.1007/BF02223384

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