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Studies on ion exchange equilibria and kinetics

VII. Tb3+−Na+ cation exchange equilibria and kinetics in zeolite-Y

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Abstract

160Tb was used as radiotracer and the equilibria and kinetics of\(3\overline {Na} + Tb^{3 + } \rightleftarrows \overline {Tb} + 3Na^ + \) cation exchange with zeolite-Y were studied. The ion exchange isothems and the Kielland plots at 298 and 303 K were obtained. It was found that the ion exchange rate is controlled by particle diffusion. The integral interdiffusion coefficients for the direct and reverse exchanges at 298 K and 303 K were calculated. In addition, the\(\overline {{}^{160}Tb} /Tb\) isotopic ion exchange was studied too.

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Zuyi, T., Quanchang, L. Studies on ion exchange equilibria and kinetics. J Radioanal Nucl Chem 223, 173–176 (1997). https://doi.org/10.1007/BF02223380

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  • DOI: https://doi.org/10.1007/BF02223380

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