Abstract
160Tb was used as radiotracer and the equilibria and kinetics of\(3\overline {Na} + Tb^{3 + } \rightleftarrows \overline {Tb} + 3Na^ + \) cation exchange with zeolite-Y were studied. The ion exchange isothems and the Kielland plots at 298 and 303 K were obtained. It was found that the ion exchange rate is controlled by particle diffusion. The integral interdiffusion coefficients for the direct and reverse exchanges at 298 K and 303 K were calculated. In addition, the\(\overline {{}^{160}Tb} /Tb\) isotopic ion exchange was studied too.
Similar content being viewed by others
References
H. S. Sherry, J. Colloid Interface Sci., 28 (1968) 288.
L. V. C. Rees, Z. Y. Tao, Zeolites, 6 (1986) 201.
A. M. Zhao, Y. Q. Zhang, W. G. Tong, X. Q. Chen, Z. Y. Tao, J. Chinese Rare Earth Soc., 6 (1988) 11.
Z. Y. Tao, A. M. Zhao, W. G. Tong, R. Xiao, X. Q. Chen, J. Radional. Nucl. Chem., 116 (1987) 35.
A. M. Zhao, Z. Y. Tao, W. G. Tong, X. Q. Chen, J. Radioanal. Nucl. Chem., 116 (1987) 49.
F. Danes, F. Wolf, Z. Phys. Chem. Leipzig, 231 (1972) 329.
S.-H. Chen, K.-J. Chao, T.-Y. Lee, IEC Res., 29 (1990) 2020.
T.-Y. Lee, T.-S. Lu, S.-H. Chen, K.-J. Chao, IEC Res., 29 (1990) 2024.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Zuyi, T., Quanchang, L. Studies on ion exchange equilibria and kinetics. J Radioanal Nucl Chem 223, 173–176 (1997). https://doi.org/10.1007/BF02223380
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02223380