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Deuteriation of chlorobenzoic acids in the presence of homogeneous platinum catalyst

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Abstract

The kinetic behavior of deuteriation of 2-chloro-, 3-chloro- and 4-chlorobenzoic acids in the presence of homogeneous platinum salt catalyst in a medium containing solution of deuteriated acetic acid in heavy water has been studied at 130°C. The quasiunimolecular H/D exchange rate constants for particular position of aromatic ring hydrogens were determined by1H NMR integration signal.

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Authors and Affiliations

  1. Department of Chemistry, Warsaw University, ul. Pasteur 1, 02-089, Warsaw, Poland

    M. Kańska & R. Kański

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  1. M. Kańska
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  2. R. Kański
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Kańska, M., Kański, R. Deuteriation of chlorobenzoic acids in the presence of homogeneous platinum catalyst. J Radioanal Nucl Chem 223, 127–132 (1997). https://doi.org/10.1007/BF02223372

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  • DOI: https://doi.org/10.1007/BF02223372

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