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Interval estimation in the determination of parameters of a kinetic model

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Abstract

The degree of uncertainty in the parameters of a kinetic model resulting from the experimental erros is discussed. For this purpose, the concept of interval estimation of the parameters is introduced and a method given for their determination. The method is illustrated in the determination of the kinetic constants for olefin dehydrogenation.

Abstract

Решается вопрос о степени неопределённости в параметрах кинетической модели, вызванной погрешностью измерений. С этой целью вводится понятие интервальных оценок по параметрам и даётся метод их определения. Метод проиллюстрирован при определении кинетических констант в реакции дегидрирования олефинов.

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References

  1. M. G. Slin'ko: Kinet. Katal.,13, 566 (1972).

    Google Scholar 

  2. S. Wilks: Mathematical Statistics. Nauka, Moscow 1967.

    Google Scholar 

  3. M. G. Slin'ko, S. I. Spivak, V. I. Timoshenko: Kinet. Katal.,13, 1570 (1972).

    Google Scholar 

  4. S. S. Gagarin, Yu. A. Kolbanovskii, L. S. Polak: in “Application of Mathematics in Physical and Chemical Kinetics”, p. 82. Nauka, Moscow 1969.

    Google Scholar 

  5. L. V. Kantorovich: Sib. Mat. Zhurn.,3, 701 (1962).

    Google Scholar 

  6. S. I. Spivak, M. G. Slin'ko, V. I. Timoshenko: Reaction Kinetics and Catalysis Letters,1, 99 (1974).

    Article  Google Scholar 

  7. S. I. Spivak, V. I. Timoshenko, M. G. Slin'ko: Dokl. Akad. Nauk SSSR,192, 580 (1970).

    Google Scholar 

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Spivak, S.I., Slinko, M.G., Timoshenko, V.I. et al. Interval estimation in the determination of parameters of a kinetic model. React Kinet Catal Lett 3, 105–113 (1975). https://doi.org/10.1007/BF02216896

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  • DOI: https://doi.org/10.1007/BF02216896

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