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Study of the chlorination of CH4 and CD4 in a CO2 laser beam

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Abstract

The chlorination of CH4 and CD4 has been studied under CO2 laser radiation. Measurements of the kinetic isotope effect indicate the separation of chain initiation and chain propagation regions under these conditions.

Abstract

Изуч⪟на реакция хлорирования CH4 и CD4 под действием излучения CO2 лазера. На основании измерения кинетического изотопного эффекта показано, что в этих условиях имеет место разделение зон зарождения и продолжения цепи.

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, 630090, Novosibirsk, USSR

    V. V. Vijin, A. N. Mikheev, A. K. Petrov & Yu. N. Molin

Authors
  1. V. V. Vijin
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  2. A. N. Mikheev
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  3. A. K. Petrov
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  4. Yu. N. Molin
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Vijin, V.V., Mikheev, A.N., Petrov, A.K. et al. Study of the chlorination of CH4 and CD4 in a CO2 laser beam. React Kinet Catal Lett 3, 79–82 (1975). https://doi.org/10.1007/BF02216892

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  • DOI: https://doi.org/10.1007/BF02216892

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