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Reaction Kinetics and Catalysis Letters

, Volume 3, Issue 1, pp 71–77 | Cite as

Kinetics of the decomposition of propylene sensitized by azoisopropane

  • L. Szirovicza
  • F. Márta
Article

Abstract

The azoisopropane-sensitized pryrolysis of propylene has been studied at temperatures from 494 to 580 K. The initial rates of formation of the main products were measured by gas chromatography. A mechanism is suggested to account for the experimental results and to evaluate k1/k21/2 for the reactions
This ratio can be given as follows

Keywords

Physical Chemistry Catalysis Propylene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Abstract

Был исследован пиролиз пропилена, инициированный азоизопропаном, при температурах 494–580°K. Измерялись начальные скорости образования важных продуктов. Полученные данные оценивались в рамках предложенного механизма. Было рассчитано отношение к1 2 1/2 для реакций:
Отношение к1 2 1/2 может быть выражено следющим образом:

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References

  1. 1.
    L. Szirovicza, F. Koszó and F. Márta: Acta Phys. et Chem. Szeged,17, 33 (1971).Google Scholar
  2. 2.
    A. F. Trotman-Dickenson and G. S. Milne: NSRDS-NBC-9, U. S. Government Printing Office, Washington, D. C. 1967Google Scholar
  3. 3.
    L. Szirovicza and F. Márta: Reaction Kinetics and Catalysis Letters,1, 417 (1974)CrossRefGoogle Scholar
  4. 4.
    R. Renaud, L. C. Leitch: Can. J. Chem.,32, 545 (1964)Google Scholar
  5. 5.
    D. M. Golden, L. W. Piszkiewicz, M. J. Perona and P. C. Beadle: J. Amer. Chem. Soc.,96, 1645 (1974)CrossRefGoogle Scholar

Copyright information

© Akadémiai Kiadó 1975

Authors and Affiliations

  • L. Szirovicza
    • 1
    • 2
  • F. Márta
    • 1
    • 2
  1. 1.Institute of General and Physical ChemistryA. József UniversitySzegedHungary
  2. 2.Gas Kinetics ResearchGroup of the Hungarian Academy of SciencesSzegedHungary

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