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Homogeneous isotope exchange between copper/II/ and copper/II/-resacetophenone phenylhydrazone complex

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Abstract

Isotope exchange of copper/II/ between bis/resacetophenone phenylhydrazone/ copper/II/ complex and copper/II/ in trin-butyl phosphate and methanol medium was studied. The experiments were carried out at different temperatures varying the concentration of both metal ion and the complex. The results show that the complex is kinetically labile. An increase in temperature increases the rate of isotope exchange. The increase in concentration also results in the enhancement of the rate of reaction.

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Authors and Affiliations

  1. Chemistry Department, College of Engineering, Sri Venkateswara University, 517 502, Tirupati, India

    T. Gangaiah & G. R. K. Naidu

Authors
  1. T. Gangaiah
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  2. G. R. K. Naidu
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Gangaiah, T., Naidu, G.R.K. Homogeneous isotope exchange between copper/II/ and copper/II/-resacetophenone phenylhydrazone complex. Journal of Radioanalytical and Nuclear Chemistry Letters 146, 37–48 (1990). https://doi.org/10.1007/BF02199270

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  • DOI: https://doi.org/10.1007/BF02199270

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