Biogeochemistry

, Volume 32, Issue 3, pp 175–194 | Cite as

Effects of watershed liming on the soil chemistry of Woods Lake, New York

  • Veronica L. Blette
  • Robert M. Newton
Article

Abstract

The effects of watershed liming on the exchange complex of a forest soil were investigated at Woods Lake, in the west-central Adirondack Park, New York. Attempts to neutralize lake acidity via direct application of calcite during the 1980"s were short-lived due to a short hydraulic retention time. The Experimental Watershed Liming Study (EWLS) was initiated to investigate watershed base addition as a potentially more long-term strategy for mitigation of lake acidity. In this paper we discuss the changes in the exchangeable soil complex which occurred in response to the calcite addition and attempt a mass balance for calcite applied to the watershed.

An extensive sampling program was initiated for the watershed study. Soil samples were collected from pits prior to and in the two years following treatment to evaluate changes in soil chemistry. Calcite addition significantly altered the exchange complex in the organic horizon. Increases in pH caused deprotonation of soil organic matter and increases in cation exchange capacity, providing additional exchange sites for the retention of added calcium. Exchangeable acidity decreased to very low values, allowing the base saturation of upper organic horizons to increase to nearly 100 percent.

Post-treatment sampling found that approximately 48 percent of the calcite remained undissolved in the soil"s Oe horizon two years later. Dissolution of the calcite was affected by field moisture conditions, with greater dissolution in wetter areas of the watershed. Mass balances calculated for calcium applied to the watershed suggest that only 4 percent of the calcium was removed through the lake outlet. Approximately 96 percent of the calcium applied remained within the watershed; as undissolved calcite, on soil exchange sites or stored in the vegetation, groundwater or surface waters of the watershed.

Key words

acid mitigation exchangeable chemistry soil acidity soil chemistry watershed liming 

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References

  1. Adams WA & Evans GM 1989) Effects of lime applications to parts of an upland catchment on soil properties and the chemistry of drainage waters. Journal of Soil Science 40 (3): 585–597Google Scholar
  2. Amrhein C & Suarez DL 1987) Calcite supersaturation in soils as a result of organic matter mineralization. Soil Science Society of America Journal 51: 932–937Google Scholar
  3. April R & Newton RM 1985) Influence of geology on lake acidification in the ILWAS watersheds. Water, Air and Soil Pollution 26: 373–386Google Scholar
  4. Aulenbach BT 1988) Streamflow generation and episodic acidification during hydrologic events at Woods Lake, Adirondack Mountains, New York. MS Thesis, 168 pp, Syracuse UniversityGoogle Scholar
  5. Blette VL 1993) The effects of watershed liming on the soils and surface waters of Woods Lake, New York. MS Thesis, 246 pp, University of Massachusetts at AmherstGoogle Scholar
  6. Blette VL & Newton RM 1996) Application of the ILWAS model to watershed liming at Woods Lake, New York. Biogeochemistry 32: 363–383 (this issue)Google Scholar
  7. Brown DJA, Howells GD, Dalziel TRK & Stewart BR 1988) Loch Fleet — A research watershed liming project. Water, Air, and Soil Pollution 41: 25–41Google Scholar
  8. Cirmo CP & Driscoll CT 1996) The impacts of a watershed CaCO3 treatment on stream and wetland biogeochemistry in the Adirondack Mountains. Biogeochemistry 32: 265–297 (this issue)Google Scholar
  9. David MB, Fuller RD, Fernandez IJ, Mitchell MJ, Rustad LE, Vance GF, Stam AC & Nodvin SV 1990 Spodosol variability and assessment of response to acidic deposition. Soil Science Society of America Journal 54: 541–548Google Scholar
  10. Davis JE & Goldstein RA 1988) Simulated response of an acidic Adirondack lake watershed to various liming mitigation strategies. Water Resources Research 24: 525–532Google Scholar
  11. Derome J 1990/91) Effects of forest liming on the nutrient status of podzolic soils in Finland. Water, Air, and Soil Pollution 54: 337–350Google Scholar
  12. Driscoll CT, Cinno CP, Fahey TJ, Blette VL, Burns DJ, Gubala CP, Newton RM, Raynal DJ, Schofield CL, Yavitt JB & Porcella DB 1996) The Experimental Watershed Liming Study (EWLS): Comparison of lake/watershed base neutralization strategies. Biogeochemistry 32: 143–174 (this issue)Google Scholar
  13. Driscoll CT, Ayling WA, Fordham GF & Oliver LM 1989) Chemical response of lakes treated with CaCO3 to reacidification, Canadian Journal of Fisheries and Aquatic Sciences 46 (2): 258–267Google Scholar
  14. Foster NW, Hogan GD & Morrison IK 1988) Growth of Jack Pine forest on an acid brunisol treated with lime, Communications in Soil Science and Plant Analysis 19: 1393–1405Google Scholar
  15. Geary R & Driscoll CT 1996) Forest soil solutions: acid/base chemistry and response to calcite treatment. Biogeochemistry 32: 195–220 (this issue)Google Scholar
  16. Gherini SA, Mok L, Hudson RJM & Davis GF 1985) The ILWAS model: Formulation and Application. Water, Air, and Soil Pollution 26: 425–459Google Scholar
  17. Grieve IC 1990 Effects of catchment liming and afforestation on the concentration and fractional composition of aluminum in the Loch Fleet catchment, SW Scotland. Journal of Hydrology 115: 385–396Google Scholar
  18. Gross MG 1971) Carbon Determination, In: Carver RJ96). Wiley-Interscience, New YorkGoogle Scholar
  19. Howells GD & Brown DJA 1986) Loch Fleet: Techniques for acidity mitigation. Water, Air and Soil Pollution 31: 817–825Google Scholar
  20. Lessmark O & Thornelof E 1986) Liming in Sweden. Water, Air and Soil Pollution 31: 809–815Google Scholar
  21. Kalisz PS & Stone EL 1980) Cation exchange capacity of acid forest humus layers. Soil Science Society of America Journal 44: 407–413Google Scholar
  22. McClean EO & Brown JR 1984) Crop response to lime in the Midwestern United States, In: Adams Fadison, WIGoogle Scholar
  23. Newton RM, Burns DA, Blette VL & Driscoll CT 1996) Effect of whole catchment liming on the episodic acidification of two Adirondack streams. Biogeochemistry 32: 299–322 (this issue)Google Scholar
  24. Nohrstedt HO 1988) Effects of liming and N-fertilization on denitrification and N2-fixation in an acid coniferous forest floor. Forest Ecology and Management 24: 1–13Google Scholar
  25. Persson R, Wiren A & Andersson S 1990 Effects of liming on carbon and nitrogen mineralization in coniferous forests. Water, Air, and Soil Pollution 54: 351–364Google Scholar
  26. Porcella DB 1989) Lake acidification mitigation project (LAMP): an overview of an ecosystem perturbation experiment. Canadian Journal of Fisheries and Aquatic Sciences 46: 246–248Google Scholar
  27. Ross DS, Bartlett RS & Magdoff FP 1991) Exchangeable cations and the pH-dependent distribution of cation exchange capacities in Spodosols of a forested watershed. In: Wright RSGoogle Scholar
  28. Santore RC, Driscoll CT & Aloi M 1994) A model of soil organic matter and its function in temperate forest soil development. In: Kelly JM & McFee WWGoogle Scholar
  29. Thomas GW 1982) Exchangeable cations, In: Page ALnd Microbiological Properties (pp 159–165). American Society of Agronomy, Madison, WIGoogle Scholar
  30. Thomas GW & Hargrove 1984) The chemistry of soil acidity, In: Adams FSociety of Agronomy, Madison, WIGoogle Scholar
  31. Tveite B, Abrahamsen G & Stuanes AO 1990/91) Liming and wet acid deposition effects on tree growth and nutrition: experimental results. Water, Air, and Soil Pollution 54: 409–422Google Scholar
  32. Westling O & Hultberg H 1990/91) Liming and fertilization of acid forest soil:short-term effects of runoff from small catchments. Water, Air, and Soil Pollution 54: 391–407Google Scholar

Copyright information

© Kluwer Academic Publishers 1996

Authors and Affiliations

  • Veronica L. Blette
    • 1
  • Robert M. Newton
    • 2
  1. 1.Department of Geology and GeographyUniversity of Massachusetts-AmherstAmherstUSA
  2. 2.Department Of GeologySmith CollegeNorthamptonUSA

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