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Thermodynamic studies of complex formation of actinyl ions extracted with TBP from hydrochloric and nitric acids

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Abstract

The changes of the free energy, enthalpy and entropy accompanying the extraction of the U/VI/, Np/VI/ and Pu/VI/ by TBP have been determined by the method of extraction chromatography. The results obtained indicate outer-sphere complexation.

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References

  1. S. Siekierski,J. Radioanal. Chem., 31 /1976/ 335.

    Google Scholar 

  2. L. Fuks, Ph. D. Thesis, Warsaw University, 1986.

  3. K. Alcock, G. F. Best, E. Hesford, H. A. C. McKay,J. Inorg. Nucl. Chem., 6 /1958/ 328.

    Google Scholar 

  4. L. Fuks, S. Lis, I. Fidelis,J. Radioanal. Chem., 52 /1979/ 79.

    Google Scholar 

  5. L. Fuks, I. Fidelis,J. Radioanal. Chem., 76 /1983/ 125.

    Google Scholar 

  6. I. Fidelis, S. Siekierski,J. Chromatogr. 17 /1965/ 542.

    PubMed  Google Scholar 

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Authors and Affiliations

  1. Institute of Nuclear Chemistry and Technology, Dorodna 16, 03-195, Warsaw, Poland

    L. Fuks & I. Fidelis

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  1. L. Fuks
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  2. I. Fidelis
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Fuks, L., Fidelis, I. Thermodynamic studies of complex formation of actinyl ions extracted with TBP from hydrochloric and nitric acids. Journal of Radioanalytical and Nuclear Chemistry Letters 118, 361–368 (1987). https://doi.org/10.1007/BF02170469

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  • DOI: https://doi.org/10.1007/BF02170469

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