Skip to main content
Log in

Gamma irradiation effects of51Cr/III/ Isotope exchange in doped magnesium chromate — zinc chromate mixtures

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Gamma irradiation effects of chromium isotope exchange in magnesium chromate — zinc chromate mixtures doped with51Cr/III/ were investigated. It was found that γ irradiation has an oxidation effect and the percentage of51Cr/VI/ exchanged increases with increasing γ-ray dose. The data were explained in terms of mechanistic model involving metal and ligand vacancies exchange and substitution reactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. D. J. Apers, K. E. Collins, C. H. Collins, Y. F. Ghoos, P. C. Capron,Radiochim. Acta, 3 /1964/ 18.

    Google Scholar 

  2. C. H. Collins, K. E. Collins, Y. F. Ghoos, D. J. Apers,Radiochim. Acta, 4 /1965/ 211.

    Google Scholar 

  3. C. H. Collins, R. E. Ackerhalt, K. E. Collins,Radiochim. Acta, 17 /1972/ 73.

    Google Scholar 

  4. b. Mohieu, D. J. Apers, P. C. Capron,Radiochim. Acta, 16 /1971/ 100.

    Google Scholar 

  5. M. I. Stamouli,Radiochim. Acta, 23 /1976/ 173.

    Google Scholar 

  6. M. I. Stamouli,Radiochim. Acta, 29 /1981/ 29.

    Google Scholar 

  7. M. I. Stamouli,Radiochim. Acta, 26 /1979/ 37.

    Google Scholar 

  8. G. Duplatre,J. Inorg. Nucl. Chem., 38 /1976/ 1769.

    Google Scholar 

  9. I. G. Ladriellf, M. A. CoGneau, D. J. Apers,Radiochim. Acta, 22 /1975/ 65.

    Google Scholar 

  10. K. E. Collins, J. C. DeAndrade, C. H. Collins,Radiochim. Acta, 29 /1981/ 117.

    Google Scholar 

  11. Mellor's Modern Inorganic Chemistry/Revised and edited by G.D. Parkes/, Longmans Press, Vol. XI, Green and Co Ltd., 1961.

  12. K. Kishore, K. S. Venkateswarlu,Radiochem. Radioanal. Lett., 7 /1971/ 263.

    Google Scholar 

  13. K. Rössler, J. Otterbach, G. Stöcklin,J. Phys. Chem., 76 /1972/ 2499.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mahfouz, R.M. Gamma irradiation effects of51Cr/III/ Isotope exchange in doped magnesium chromate — zinc chromate mixtures. Journal of Radioanalytical and Nuclear Chemistry Letters 87, 137–142 (1984). https://doi.org/10.1007/BF02169240

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02169240

Keywords

Navigation