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Determination of activation energies in the annealing of cobalt recoil atoms in single and double complexes

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Abstract

Activation energies for the recombination of point defects generated by the /n,γ/ reaction in Ba (CoEDTA)2·4H2O, t-(Co(en)2(NO2)2)Cl and (Co(en)2(NO2)2) (CoEDTA)·1H2O, have been evaluated using isothermal step annealing. The reselts were interpreted in terms of compound structures. It is possible to relate the recoil atom behaviour between single complexes and the double one.

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References

  1. N. Saito, T. Tominaga, H. Sano,Nature, 194 /1962/ 466.

    PubMed  Google Scholar 

  2. G. Harbottle, Chemical Effects of Nuclear Transformations, I.A.E.A., Vienna, 1 /1961/ 301.

    Google Scholar 

  3. G. E. Boyd, Q. V. Larson,J. Am. Chem. Soc., 90 /1968/ 254.

    Google Scholar 

  4. M. T. A. Teeling, A. H. W. Aten Jr., J. Boersma, P. W. F. Louwrier, D. J. Apers,J. Inorg. Nucl. Chem., 43 /1981/ 3043.

    Google Scholar 

  5. B. Meriadeg, M. Milman,J. Inorg. Nucl. chem., 33 /1971/ 915.

    Google Scholar 

  6. A. L. Fantola-Lazzarini, E. Lazzarini,J. Inorg. Nucl. Chem., 35 /1973/ 681.

    Google Scholar 

  7. M. T. A. Teeling, A. H. W., Aten, Jr., P. W. F. Louwrirer, J. Boersma, D. J. Apers,J. Inorg. Nucl. Chem., 43 /1981/ 3047.

    Google Scholar 

  8. A. W. Overhauser,Phys. Rev., 90 /1953/ 393.

    Google Scholar 

  9. R. O. Marques, Thesis, Universidad Nacional de Buenos Aires, 1972.

  10. Inorganic Synthesis, 1946–1965, McGraw Hill, London.

  11. F. Basolo,J. Am. Chem. Soc., 72 /1950/ 4393.

    Google Scholar 

  12. M. L. Morris, D. H. Busch,J. Am. Chem. Soc., 82 /1960/ 1521.

    Google Scholar 

  13. M. Maki,Japan Analyst, 4 /1955/ 217.

    Google Scholar 

  14. A. L. Fantola-Lazzarini, E. Lazzarini,J. Inorg. Nucl. Chem., 35 /1973/ 2653.

    Google Scholar 

  15. T. Costea, I. Negoescu,J. Inorg. Nucl. Chem., 28 /1966/ 326.

    Google Scholar 

  16. See for example, G. H. Vineyard,Dis. Faraday Soc., 31 /1961/ 7.

    Google Scholar 

  17. V. Vand,Proc. Phys. Soc., 55 /1953/ 222.

    Google Scholar 

  18. W. Primak,Phys. Rev., 100 /1955/ 1677.

    Google Scholar 

  19. C. Di Risio, R. O. Marques,J. Radioanal. Nucl. Chem., Lett., 94 /1985/ 191.

    Google Scholar 

  20. C. Di Risio, R. O. Marques,J. Radioanal. Nucl. Chem., Lett., 94 /1985/ 399.

    Google Scholar 

Download references

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Authors and Affiliations

  1. Departmento de Química Inorgánica, Analítica y Química Física, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Buenos Aires, Argentina

    C. Di Risio & R. O. Marques

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  1. C. Di Risio
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  2. R. O. Marques
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Di Risio, C., Marques, R.O. Determination of activation energies in the annealing of cobalt recoil atoms in single and double complexes. Journal of Radioanalytical and Nuclear Chemistry Letters 118, 235–243 (1987). https://doi.org/10.1007/BF02167369

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  • DOI: https://doi.org/10.1007/BF02167369

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