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Solvent effects on the37Cl/n,γ/38Cl reaction products of some solid chlorobenzene derivatives

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Abstract

Phase change effects on the total organic yield have been studied in crystalline chlorobenzene derivatives activated by radiative neutron capture. Irradiation of the compounds in benzene solution decreased the organic yield considerably while these values remained unchanged when 1∶1 benzene + DMSO or 1∶1 benzene + acetonitrile solvent mixtures were used, the 1∶1 benzene + THF solvent gave the lowest yield in all the cases. Heat treatment to the neutron activated solids enhanced the organic yield only in the case of 2-amino 5-chlorobenzophenone by ∼7%.

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Authors and Affiliations

  1. Department of Chemistry, University of Poona, 411 007, Pune, India

    V. G. Dedgaonkar, S. Mitra & Sunil Waghmare

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  1. V. G. Dedgaonkar
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  2. S. Mitra
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  3. Sunil Waghmare
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Dedgaonkar, V.G., Mitra, S. & Waghmare, S. Solvent effects on the37Cl/n,γ/38Cl reaction products of some solid chlorobenzene derivatives. Journal of Radioanalytical and Nuclear Chemistry Letters 87, 373–378 (1984). https://doi.org/10.1007/BF02166795

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  • DOI: https://doi.org/10.1007/BF02166795

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