Advertisement

Journal of Radioanalytical and Nuclear Chemistry

, Volume 103, Issue 3, pp 141–151 | Cite as

The influence of iodine on radiolysis of Purex-solvent

  • M. Nowak
  • Z. Nowak
Article

Abstract

The effect of stable iodine on the radiolysis of the TBP-dodecane solvent was examined at two nitric acid concentrations. The results obtained indicate that presaturation of the solvent with stable iodine causes marked increase in the yields of organic nitrites and hydroxy-compounds and decrease of the yield of HDBP, carbonyl and nitro-compounds. The mechanisms of observed effects are discussed.

Keywords

Physical Chemistry Inorganic Chemistry Iodine Nitrite Carbonyl 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Spravotechnik: Radiatsionnye kharakteristiki obluchennovo yadernovo topliva, Energoatomizdat, Moskva, 1983.Google Scholar
  2. 2.
    Ch.A. Blake, Jr., Report ORNL-4212, 1986.Google Scholar
  3. 3.
    J. Canva, M. Pagès,Bull. Soc. Chim. France, 5 /1964/ 909.Google Scholar
  4. 4.
    P.A. Zagoretsh et al.,Atomnaya Energ., 34 /1973/ 205.Google Scholar
  5. 5.
    K. Alcock et al.,Trans. Faraday Soc., 52 /1956/ 39.Google Scholar
  6. 6.
    M. Nowak, Z. Nowak et al., Proceedings of IV Comeco Symposium, Prague, 1977, Vol. III, p. 52.Google Scholar
  7. 7.
    T.P. Garrett, Report DP-237, 1957.Google Scholar
  8. 8.
    C.A. Horton, J.C. White,Talanta, 7 /1961/ 215.Google Scholar
  9. 9.
    M. Nowak, Report INR-1901 /XXII/C/B, 1981.Google Scholar
  10. 10.
    R.W. Wilkinson, T.J. Williams,J. Chem. Soc., /1961/ 4098.Google Scholar
  11. 11.
    J.G. Burr,Radiation Res., 8 /1958/ 214.Google Scholar
  12. 12.
    A. Kirrman, J. Cantacuzne, P. Duhamel, Chemic Organique, Polish transl., ed. PWN Warszawa 1975, pp. 221–222.Google Scholar
  13. 13.
    K.J. Laidler, The Chemical Kinetics of Excited States, Polish transl., ed. PWN Warszawa 1983, pp. 144–159.Google Scholar
  14. 14.
    J. Kroch, Chemia Radiacyjna, PWN Warszawa 1970, pp. 117–120.Google Scholar
  15. 15.
    F. Feigl, Spot Test in Organic Analysis, Elsevier, Amsterdam, 1956, pp. 83–84.Google Scholar
  16. 16.
    L.A. Fieser, M. Fieser, Advanced Organic Chemistry, Reinhold Publ., New York, 1963, pp. 156–157.Google Scholar
  17. 17.
    P. Merkl, L. Heunblett, P. Wichman, Report ETR-220, 1964.Google Scholar
  18. 18.
    J.R. Park, D.L. Williams,J. Chem. Soc., /1972/ 2158.Google Scholar

Copyright information

© Akadémiai Kiadó 1986

Authors and Affiliations

  • M. Nowak
    • 1
  • Z. Nowak
    • 1
  1. 1.Institute of Atomic EnergySwierkPoland

Personalised recommendations