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Mössbauer study on the photolysis of pentacarbonyliron isolated in low temperature nitrogen matrix by continuous or pulsed deposition

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Abstract

The UV photolysis of pentacarbonyliron isolated in low temperature nitrogen matrix by continuous or pulsed deposition was studied by means of Mössbauer technique. Unstable species such as Fe/CO/n /n=2–4/ were produced by UV irradiation and their Mössbauer parameters were measured. The yields of unstable species were found to be influenced by the deposition method of nitrogen matrix.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo, Japan

    Y. Yamada & T. Tominaga

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  1. Y. Yamada
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  2. T. Tominaga
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Yamada, Y., Tominaga, T. Mössbauer study on the photolysis of pentacarbonyliron isolated in low temperature nitrogen matrix by continuous or pulsed deposition. Journal of Radioanalytical and Nuclear Chemistry Letters 118, 119–128 (1987). https://doi.org/10.1007/BF02166268

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  • DOI: https://doi.org/10.1007/BF02166268

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