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129I-Mössbauer spectroscopic studies of ferricinium, biferrocenium and 1′, 1′''-dihalobiferrocenium iodides

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Abstract

129I-Mössbauer spectroscopic data are presented for the titled iodides. Comparison of Mössbauer parameters of the mixed-valence biferrocenium iodides suggests that the rate of intramolecular electron transfer depends on the nature of biferrocenium cation moiety in solid state.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Tokyo Metropolitan University, Fukasawa, Setagaya-ku, 158, Tokyo, Japan

    M. Katada, S. Nakashima, Y. Uchida, I. Motoyama & H. Sano

  2. Research Reactor Institute, Kyoto University, Kumatori-cho, Sennan-gun, 590-04, Osaka, Japan

    H. Sakai & Y. Maeda

Authors
  1. M. Katada
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  2. S. Nakashima
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  3. Y. Uchida
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  4. I. Motoyama
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  5. H. Sano
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  6. H. Sakai
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  7. Y. Maeda
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Katada, M., Nakashima, S., Uchida, Y. et al. 129I-Mössbauer spectroscopic studies of ferricinium, biferrocenium and 1′, 1′''-dihalobiferrocenium iodides. Journal of Radioanalytical and Nuclear Chemistry Letters 104, 349–358 (1986). https://doi.org/10.1007/BF02166221

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  • DOI: https://doi.org/10.1007/BF02166221

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