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Reaction of13N produced by recoil deuterons in pile-irradiated acetic acid-d4 and malonic acid-d4

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Abstract

The reaction of13N to form13N-labelled compounds was studied in acetic acid-d4 as a function of the halogenoacetic acid concentration and in malonic acid-d4 as a function of the intermolecular distance of target malonic acid-d4 at 195 and 295±6 K. In both deuterated carboxylic acids,13N atoms were found in several forms in the order of radiochemical yields,13NH3>H13NO3>[13N]aminoacid>HC13N. The yield of [13N]glycine formed in acetic acid-d4 were markedly enhanced by iodoacetic acid and slightly by chloroacetic acid. In malonic acid-d4, the yield of13NH3 was directly proportional to the cubic root of the molar ratio, {D2O/CD2 (COOD)2}, while the yields of H13N3, [13N]aminomalonic acid and HC13N were inversely proportional to the cubic root of the molar ratio. The mechanism of the formation of the13N-compounds are discussed.

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Authors and Affiliations

  1. Faculty of General Education, Rikkyo University, Nishi-Ikebukuro 3-34-1, 171, Tokyo, Japan

    Y. Sensui

  2. Institute for Atomic Energy, Rikkyo University, nagasaka 2-5-1, 240-21, Yokosuka, Japan

    K. Tomura, I. Nakakuki & H. Suzuki

Authors
  1. Y. Sensui
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  2. K. Tomura
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  3. I. Nakakuki
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  4. H. Suzuki
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Sensui, Y., Tomura, K., Nakakuki, I. et al. Reaction of13N produced by recoil deuterons in pile-irradiated acetic acid-d4 and malonic acid-d4 . Journal of Radioanalytical and Nuclear Chemistry Letters 118, 23–31 (1987). https://doi.org/10.1007/BF02165651

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  • DOI: https://doi.org/10.1007/BF02165651

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