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Chemical consequences of the /n, γ/ reaction in diphenyl selenium

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Abstract

The products formed during thermal neutron irradiation of diphenyl selenium have been analyzed by gas chromatography. Possible reaction mechanisms are discussed to explain the principal reaction product observed. The organic yields of75Se,83Se and81mSe formed have been determined. The retention values obtained were 9.7±2.0, 8.3±1.1 and 10.4±2.1, respectively. These low values indicate that in all three cases most of the molecules are broken after the /n, γ/ process. No isotope effect was observed.

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Authors and Affiliations

  1. Instituto Nacional de Investigaciones Nucleares, Agricultura 21, 11800, México, D. F., México

    C. Beltrán & S. Bulbulian

  2. UNAM, Circuito exterior, C. U. Delegación Coyoacán, Centro de Estudios Nucleares, 04510, México, D. F., México

    C. Archundia

Authors
  1. C. Beltrán
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  2. S. Bulbulian
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  3. C. Archundia
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Beltrán, C., Bulbulian, S. & Archundia, C. Chemical consequences of the /n, γ/ reaction in diphenyl selenium. Journal of Radioanalytical and Nuclear Chemistry Letters 96, 59–67 (1985). https://doi.org/10.1007/BF02165586

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  • DOI: https://doi.org/10.1007/BF02165586

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