Skip to main content
SpringerLink
Log in

Reaction of neptunyl ions with mycobactin S in nonaqueous medium

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Addition of solutions of mycobactin S in acetone or methanol/acetone mixtures to solutions of NpO 2+2 in the same solvent leads to the immediate reduction of neptunium/VI/ to neptunium/V/. Np/V/ interacts with the ionophore to form a yellow complex with a cation: ligand ratio of 2∶1. The course of these reactions is followed by measurement of changes in characteristic optical absorption and by spectrophotometric titration within the range 700–1350 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. G.A. Snow,Bacteriol. Rev., 34 /1970/ 99.

    PubMed  Google Scholar 

  2. S. Wendenbaum, Structure du Sidérophore de Pseudomonas Aeruginosa, Thèse, Université Louis-Pasteur, Strasbourg, 1983.

    Google Scholar 

  3. H.J. MacCordick,J. Radioanal. Nucl. Chem., Lett., 126 /1988/ 173.

    Google Scholar 

  4. H.J. MacCordick,Dossier Technique, CRN/CPR-84-6, Centre de Recherches Nucléaires, Strasbourg, 1984, and references therein.

    Google Scholar 

  5. H.J. MacCordick, J.J. Schleiffer, G. Duplâtre,Radiochim. Acta, 38 /1985/ 43.

    Google Scholar 

  6. H.J. MacCordick, J.P. Adloff,Radiochem. Radioanal. Lett., 14 /1973/ 341.

    Google Scholar 

  7. Gmelin Handbuch der Anorganischen Chemie, 8, Aufl., Erg. Bd. 20, Transurane Dl, Springer-Verlag, Berlin, 1975, S. 37, 38.

  8. Gmelin Handbuch der Anorganischen Chemie, 8, Aufl., Erg. Bd. 20, Transurane Dl, Springer-Verlag, Berlin, 1975, S. 39.

  9. R. Gauthier, V. Ilmstädter, K.H. Lieser,Radiochim. Acta, 33 /1983/ 35.

    Google Scholar 

  10. U. Casellato, M. Vidali, P.A. Vigato,Inorg. Chim. Acta, 18 /1976/ 77, and references therein.

    Article  Google Scholar 

  11. C. Keller, S.H. Eberle,Radiochim. Acta, 8 /1967/ 65.

    Google Scholar 

  12. S.H. Eberle, U. Wede,J. Inorg. Nucl. Chem., 32 /1970/ 109.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie Nucléaire, Centre de Recherches Nucléaires et Université Louis-Pasteur, B.P. 20, F-67037, Strasbourg Cedex, France

    H. J. MacCordick & M. Kadri

Authors
  1. H. J. MacCordick
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Kadri
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

MacCordick, H.J., Kadri, M. Reaction of neptunyl ions with mycobactin S in nonaqueous medium. Journal of Radioanalytical and Nuclear Chemistry Letters 127, 51–58 (1988). https://doi.org/10.1007/BF02165505

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02165505

Keywords

Search

Navigation