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A study on the solvent extraction of Pd/II/ with 1,2,3-benzotriazole into methyl iso-butyl ketone

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Abstract

A novel method has been developed for the extraction of Pd/II/ with 1,2,3-benzotriazole /1,2,3-BT/ into methyl isobutyl ketone /MIBK/ at a pH of 4.0. The effects of pH, time of equilibration, solvent, anions and cations on the extraction coefficient have been evaluated. The stoichiometry of the extracted species of 1∶2 was obtained by the slope ratio method and by the method of substoichiometric extraction. Separation factors and decontamination factors for a number of elements in the extraction of Pd/II/ were also obtained.

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References

  1. K. L. Cheng,Anal. Chem., 26 /1954/ 1038.

    Google Scholar 

  2. W. J. Remington, H. V. Moyer,Dissertation Abstr., 24 /1937/.

  3. J. A. Curtis,Anal. Chem., 13 /1941/ 349.

    Google Scholar 

  4. R. F. Wilson, L. E. Wilson,Anal. Chem., 28 /1956/ 93.

    Google Scholar 

  5. A. I. Vogel, Textbook of Quantitative Inorganic Analysis, Longmans Green and Co. Ltd., London, 1975.

    Google Scholar 

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Authors and Affiliations

  1. Nuclear Chemistry Division, The Institute of Science, 15, Madam Cama Road, 400 032, Bombay, India

    I. A. Mendes & Z. R. Turel

Authors
  1. I. A. Mendes
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  2. Z. R. Turel
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Mendes, I.A., Turel, Z.R. A study on the solvent extraction of Pd/II/ with 1,2,3-benzotriazole into methyl iso-butyl ketone. Journal of Radioanalytical and Nuclear Chemistry Letters 104, 43–51 (1986). https://doi.org/10.1007/BF02165420

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  • DOI: https://doi.org/10.1007/BF02165420

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