Advertisement

Solvoluminescence from γ-irradiated lithium chloride

  • A. V. Khedekar
  • C. D. Kalkar
  • A. S. Banerji
Article

Abstract

Solvoluminescence /SL/ of γ-irradiated LiCl crystals have been studied in some organic solvents. The SL emission spectra of LiCl crystals were recorded in N-methyl acetamide, nitrobenzene, cyclohexanol, cyclohexanone and pure water. The total SL intensity of LiCl in various organic solvents was found to vary with the type and nature of the solvent. The results are explained on the basis of the electron-scavenging effect and complexing abilities of the solvents.

Keywords

Chloride Physical Chemistry Lithium Inorganic Chemistry Organic Solvent 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    E. Wiedemann, G. C. Schmidt,Ann. d. Physik., 56 /1895/ 210.Google Scholar
  2. 2.
    G. Ahnström, G. V. Ehrenstein,Acta Chem. Scand., 13 /1959/ 855.Google Scholar
  3. 3.
    T. Westermark, B. Grapengiesser,Nature, 188 /1960/ 395.Google Scholar
  4. 4.
    H.J. Arnikar, P.S. Damle, B.D. Chaure,J. Chem. Phys., 55 /1971/ 3668.Google Scholar
  5. 5.
    N.A. Atari, K.V. Ettinger,Nature, 249 /1974/ 341.Google Scholar
  6. 6.
    H.J. Arnikar, A.V. Khedekar, A.S. Banerji,J. Chim. Phys., 74 /1977/ 19.Google Scholar
  7. 7.
    A. Weissberger, Organic Solvents, Interscience Publishers Ltd., 2nd Ed., London, 1955.Google Scholar
  8. 8.
    H. Sisler, Chemistry of Non Aqueous Solvents, Chapman and Hall Ltd., London, 1965, p. 103.Google Scholar
  9. 9.
    H. Stephen, T. Stephen Ed., Solubilities of Inorganic and Organic Compounds, Vol. I, Part I, Pergamon Press, London, 1963.Google Scholar
  10. 10.
    H.J. Arnikar, P.S. Damle, B.D. Chaure, Vijaya Deo,J. Poona Univ. Sci. and Tech., 40 /1971/ 11.Google Scholar
  11. 11.
    L. Pauling, The Nature of Chemical Bond, Cornell Univ. Press, Ithaca, N.Y. 1966, pp. 98–99.Google Scholar
  12. 12.
    T.Q. Nguyen,Can. J. Chem., 57 /1979/ 1758.Google Scholar
  13. 13.
    K.V. Ettinger, N.A. Atari, J.R. Mallard, Proc. Int. Conf. Lum. Dosim. 5th, 1977, 40.Google Scholar
  14. 14.
    C.D. Kalkar,J. Radioanal. Nucl. Chem. Lett., 86 /1984/ 65.Google Scholar
  15. 15.
    C.D. Kalkar,Radiochem. Radioanal. Lett., 58 /1983/ 317.Google Scholar
  16. 16.
    E. Watson, S. Roy, Selected specific rates of reactions of the solvated electrons in alcohols, NSRDS-NBS 42, 1972.Google Scholar
  17. 17.
    M. Clavas, T. Ribar,Glas. Hem. Technol., Boshe Hercegovine, 16/ 1968/ 123.Google Scholar
  18. 18.
    S. Berk, H. Geisser,Radiat. Res., 56 /1973/ 71.Google Scholar

Copyright information

© Akadémiai Kiadó 1985

Authors and Affiliations

  • A. V. Khedekar
    • 1
  • C. D. Kalkar
    • 1
  • A. S. Banerji
    • 1
  1. 1.Department of ChemistryUniversity of PoonaPuneIndia

Personalised recommendations