The radiolysis of aqueous solution of bis/1,2-dicarbollyl/cobalt/III/ acid

  • Ľ. Mátel
  • Ľ. Vašeková
  • P. Račay
Article

Abstract

The radiation-induced oxidation of bis/1,2-dicarbollyl/cobalt/III/ acid by OH radicals in deaerated/aerated aqueous solutions has been investigated. 8-Monohydroxy-, and 8,8′-dihydroxy-derivatives have been identified as products of the γ-radiolysis. For the different conditions the following radiationchemical yields were observed: in the presence of N2 atmosphere G/OHDCC/=1.58, in aerated solution 2.11 and 3.04 in a solution saturated with CCl3.

Keywords

Oxidation Atmosphere Physical Chemistry Aqueous Solution Inorganic Chemistry 

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Copyright information

© Akaémiai Kiadó 1988

Authors and Affiliations

  • Ľ. Mátel
    • 1
  • Ľ. Vašeková
    • 1
  • P. Račay
    • 1
  1. 1.Department of Nuclear ChemistryComenius UniversityBratislavaCzechoslovakia

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