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Mössbauer study of crystalline FeSO3.3H2O and its frozen aqueous solution

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Abstract

57Fe Mössbauer measurements were performed on FeSO3 being in frozen solution and in crystalline states. The obtained typical Mössbauer parameters for crystalline FeSO3.3H2O are IS=1.23±0.05 mm s−1 and QS=2.50±0.01 mm s−1, while for the fozen solution: IS=1.32±0.01 mm s−1, QS=3.24±0.01 mm s−1. It show that FeII is hexaaquacoordinated in the solution.

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Authors and Affiliations

  1. Laboratory of Nuclear Chemistry, L. Eötvös University, Budapest, Hungary

    E. Kuzmann, Cs. Vértes & A. Vértes

  2. Department of General and Anorganic Chemistry, L. Eötvös University, Budapest, Hungary

    M. Gál

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  1. E. Kuzmann
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  2. M. Gál
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  3. Cs. Vértes
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  4. A. Vértes
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Kuzmann, E., Gál, M., Vértes, C. et al. Mössbauer study of crystalline FeSO3.3H2O and its frozen aqueous solution. Journal of Radioanalytical and Nuclear Chemistry Letters 145, 339–343 (1990). https://doi.org/10.1007/BF02165074

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  • DOI: https://doi.org/10.1007/BF02165074

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