Skip to main content
SpringerLink
Log in

Effect of nitrate ions on the oxidation of iodide ions during the dissolution of γ-irradiated NaCl in aqueous binary mixture of iodide and nitrate

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

It is now well established that the oxidation of iodide ions and the reduction of nitrate ions take place when γ-irradiated sodium chloride is dissolved in aqueous iodide and nitrate solutions, respectively. The yield of iodine decreases and that of nitrite increases with increasing concentration of nitrate in a binary mixture of iodide and nitrate when the irradiated salt is dissolved in it. The results are explained on the basis of the reactions of colour centres with iodide and nitrate ions present in the binary mixture.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. C.D. Kalkar, A.M. Deshpande, S.V. Doshi,Radiochem. Radioanal. Lett., 57 /1983/ 329.

    Google Scholar 

  2. S. F. Patil, D. Ravishankar, P. Bhatia, I.B. Chowdhary,Int. J. Appl. Radiat. Isotopes, 35 /1984/ 459.

    Google Scholar 

  3. C.D. Kalkar, V.H. Rane, Varsha Patil,Int. J. Appl. Radiat. Isotopes /in press/.

  4. D. Ravishankar, R.N. Bhave,J. Radioanal. Nucl. Chem., Lett., 87 /1984/ 331.

    Google Scholar 

  5. H.J. Arnikar, B.S.M. Rao, A.S. Gijare, S.S. Sardesai,J. Chim. Phys., 72 /1975/ 655.

    Google Scholar 

  6. H.H. Willard, L.L. Merritt, J.A. Dean, Instrumental Methods of Analysis, 5th Ed., /1977/ 736.

  7. M.B. Shinn,Ind. Eng. Chem. Anal. Ed., /1941/ 1333.

  8. E.J. Hart, M. Anbar, Hydrated Electron, John Wiley Interscience, 1970.

  9. J.K. Thomas, S. Gordon, E.J. Hart,J. Phys. Chem., 68 /1964/ 1524.

    Google Scholar 

  10. P. Neta, Ph.D. Thesis, Rehovoth, 1965.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Poona, 411 007, Pune, India

    C. D. Kalkar & S. V. Doshi

Authors
  1. C. D. Kalkar
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. V. Doshi
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kalkar, C.D., Doshi, S.V. Effect of nitrate ions on the oxidation of iodide ions during the dissolution of γ-irradiated NaCl in aqueous binary mixture of iodide and nitrate. Journal of Radioanalytical and Nuclear Chemistry Letters 127, 161–167 (1988). https://doi.org/10.1007/BF02164861

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02164861

Keywords

Search

Navigation