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Photolysis of water-carbon tetrachloride and water-chlorobenzene saturated solutions and their two-phase systems. Quantum yields of chloride ions

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Abstract

The quantum yields of formation of chloride ions were determined in photolysis (λ=254 nm) of watercarbon tetrachloride organic phase of ΦCCl4(Cl−)=0.89±0.04 water-chlorobenzene (ΦPhCl(Cl−)=0.137± ±0.005) two-phase systems and saturated aqueous solutions of carbon tetrachloride (ΦCCl4(Cl−)=18.9±5.6 and chlorobenzene ΦPhCl(Cl−)=0.56±0.03. The quantum yields of chloride ions obtained from these systems are compared with partial radiation yields in the same systems. A mechanism for formation of Cl− ions is proposed.

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References

  1. A.L. Pruden, D.F. Ollis,J. Catal., 82 (1983) 404.

    Google Scholar 

  2. N. Getoff,Appl. Radiat. Isot., 40 (1989) 585.

    Google Scholar 

  3. N. Getoff,Radiat. Phys. Chem., 35 (1990) 432.

    Google Scholar 

  4. P. Gehringer, E. Proksch, W. Szinovatz,Int. J. Appl. Isot., 36 (1985) 313.

    Google Scholar 

  5. P. Gehringer, E. Proksch, W. Szinovatz, H. Eschweiler,Appl. Radiat. Isot., 39 (1988) 1227.

    Google Scholar 

  6. E. Proksch, P. Gehringer, W. Szinovatz, H. Eschweiler,Appl. Radiat. Isot., 4039 (1989) 133.

    Google Scholar 

  7. P. Geringer, E. Proksch, H. Eschweiler, W. Szinovatz,Radiat. Phys. Chem., 35 (1990) 456.

    Google Scholar 

  8. R. Čech, F. Macášek, L. Mátel, J. Kuruc, P. Račay, Radiation stability of solutions of dicarbollide of cobalt (III) in two-phase systems. In: Research in reprocessing of irradiated fuel and disposal of radioactive wastes. 6th Symposium of COMECOM. Czecho-Slovak Atom. Energy Commis., Piešťany, 1985. Preprint. (in Russian).

    Google Scholar 

  9. I. Dvornik, U. Zec, F. Ranogajec, In: Food Irradiation. Vienna, IAEA, 1966, p. 81–90.

    Google Scholar 

  10. R. Čech, H. Chrenčíková, V. Širáňová, J. Kuruc, F. Macášek,J. Radioanal. Nucl. Chem., Lett., 86 (1984) 337.

    Google Scholar 

  11. J. Kuruc, R. Čech,Radiochem. Radioanal. Lett., 57 (1983) 169.

    Google Scholar 

  12. J. Kuruc,J. Radioanal. Nucl. Chem., Articles, 82 (1984) 93.

    Google Scholar 

  13. J. Kuruc, A. Hlatká, R. Čech, In: International Meeting on Radiation Chemistry and Processing. Brdička Days 1986. 20th Czechoslovak Meeting. Spa Mariánské Lázně, April 21–25, 1986. Abstracts p. 18.

  14. J. Kuruc, A. Hlatká, R. Čech,Radiat. Phys. Chem., 28 (1986) 467.

    Google Scholar 

  15. R. Čech, P. Račay, F. Macášek,Radiat. Phys. Chem., 33 (1989) 109.

    Google Scholar 

  16. J. Kuruc, A. Hlatká,J. Radioanal. Nucl. Chem., Lett., 166 (1992) 151.

    Google Scholar 

  17. J. Calvert, J. Pitts. Photochemistry, Mir Publishers, Moscow, 1968, p. 625 (in Russian).

    Google Scholar 

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Authors and Affiliations

  1. Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University, CS-84215, Bratislava, Slovakia, ČSFR

    J. Kuruc & A. Hlatká

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  1. J. Kuruc
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  2. A. Hlatká
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Kuruc, J., Hlatká, A. Photolysis of water-carbon tetrachloride and water-chlorobenzene saturated solutions and their two-phase systems. Quantum yields of chloride ions. Journal of Radioanalytical and Nuclear Chemistry Letters 166, 239–250 (1992). https://doi.org/10.1007/BF02164747

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  • DOI: https://doi.org/10.1007/BF02164747

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