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Physico-chemical studies on characterization of solid state product between iron/II/ oxalate dihydrate and p-chloro aniline hydrochloride

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Abstract

Solid state reactivity between iron/II/oxalate dihydrate, i.e., FeC2O4.2H2O and para-chloro aniline hydrochloride, i.e., p-ClC6H4NH2.HCl has been studied at 373, 393 and 413 K. The reaction seems to follow the diffusion controlled mechanism. The product, [FeCl/oxH/.AN−Cl], has been characterized by elemental analysis, infrared and Mössbauer spectroscopic techniques, mass spectrometry and derivatographic methods /TG, DTA/.

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References

  1. R.P. Rastogi, A.K. Singh, C.S. Shukla,J. Solid State Chem., 42 /1982/ 136.

    Google Scholar 

  2. A.O. Patil, D.Y. Curtin, I.C. Paul,J. Am. Chem. Soc., 106 /1984/ 349.

    Google Scholar 

  3. P.S. Bassi, B.R. Gupta, I.B. Sharma,Proc. Indian Acad. Sci., /Chem. Sci./, 89 /1980/ 125.

    Google Scholar 

  4. P.S. Bassi, G.S. Chopra,J. Solid State Chem., 62 /1986/ 253.

    Google Scholar 

  5. D.C. Champaney,Phys. Bulletin, 21 /1970/ 248.

    Google Scholar 

  6. Norbert Adolph Lange, Handbook of Chemistry, 11th Ed., McGraw-Hill Book Co., U.K., 1973.

    Google Scholar 

  7. P.P. Singh, R. Rivest,Canad. J. Chem., 46 /1968/ 1773.

    Google Scholar 

  8. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 2nd Ed., J. Wiley and Sons, New York, 1970, p. 221.

    Google Scholar 

  9. D.H. Williams, I. Fleming, Spectroscopic Methods in Organic Chemistry, McGraw-Hill Book Co., U.K., 1973.

    Google Scholar 

  10. T. Birchall,Canad. J. Chem., 47 /1969/ 1351.

    Google Scholar 

  11. A.S. Brar, K.S. Khabra,Indian J. Chem., 21A /1982/ 920.

    Google Scholar 

  12. P.K. Gallagher, C.R. Kurkjian,Inorg. Chem., 5 /1966/ 214.

    Google Scholar 

  13. K.S. Singwi, A. Sjolander,Phys. Rev., 120 /1960/ 1093.

    Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India

    B. S. Randhawa & Anandpal Singh

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  1. B. S. Randhawa
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  2. Anandpal Singh
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Randhawa, B.S., Singh, A. Physico-chemical studies on characterization of solid state product between iron/II/ oxalate dihydrate and p-chloro aniline hydrochloride. Journal of Radioanalytical and Nuclear Chemistry Letters 127, 87–98 (1988). https://doi.org/10.1007/BF02164598

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  • DOI: https://doi.org/10.1007/BF02164598

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