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A119Sn-Mössbauer study of tetramethylstannane isolated in low temperature argon matrix

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Abstract

Unusually broad119Sn-Mössbauer absorption was observed in pure Sn(CH3)4 or Sn(CH3)4/argon condensed at low temperatures by pulsed deposition. Such broadening of the Mössbauer linewidth suggested the presence of large quadrupole splitting due to possible distortion of molecular structure as deposited in the argon matrix.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Tokyo, 113, Hongo, Tokyo, Japan

    H. Sato & T. Tominaga

  2. Department of Chemistry, Faculty of Science, Science University of Tokyo, 162, Kagurazaka, Tokyo, Japan

    C. Obayashi

Authors
  1. C. Obayashi
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  2. H. Sato
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  3. T. Tominaga
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Obayashi, C., Sato, H. & Tominaga, T. A119Sn-Mössbauer study of tetramethylstannane isolated in low temperature argon matrix. Journal of Radioanalytical and Nuclear Chemistry Letters 127, 75–85 (1988). https://doi.org/10.1007/BF02164597

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  • DOI: https://doi.org/10.1007/BF02164597

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