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Structures of chlorotrimethylstannane Sn/CH3/3Cl dispersed in various matrices

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Abstract

The structure of chlorotrimethylstannane was studied by Mössbauer spectroscopy in solids, frozen solution, and argon matrices at low temperatures. In frozen solutions, quadrupole splitting was very similar to the value in solid phase, and strong intermolecular interaction may exist between Sn/CH3/3Cl and solvent molecules. In argon matrices, the quadrupole splitting of Sn/CH3/3Cl was much smaller. Comparison of the observed quadrupole splitting with the predicted value based on the point charge model suggests that the Sn/CH3/3Cl molecule may have a tetrahedral structure and be isolated well from each other in the argon matrix.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, The University of Tokyo, 113, Hongo, Tokyo, Japan

    C. Obayashi & T. Tominaga

  2. Department of Chemistry, Faculty of Science, Science University of Tokyo, 162, Kagurazaka, Tokyo, Japan

    H. Sato

Authors
  1. C. Obayashi
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  2. H. Sato
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  3. T. Tominaga
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Obayashi, C., Sato, H. & Tominaga, T. Structures of chlorotrimethylstannane Sn/CH3/3Cl dispersed in various matrices. Journal of Radioanalytical and Nuclear Chemistry Letters 137, 87–96 (1989). https://doi.org/10.1007/BF02164571

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  • DOI: https://doi.org/10.1007/BF02164571

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