Abstract
Dianionic tridentate O, N, S Schiff bases derived from salicylaldehyde and 2-mercaptoamines react with Tc/V/ gluconate to form radiochemically pure neutral Tc chelates. The existence of lipophilic Tc complexes could be proved by high voltage electrophoresis, thin layer chromatography and octanol/water partition coefficients.
Similar content being viewed by others
References
W.H. Oldendorf,J. Nucl. Med., 19 /1978/ 1182.
M.D. Loberg, E.H. Corder, A.T. Fields, P.S. Callery,J. Nucl. Med., 20 /1979/ 1181.
M. Kato-Azuma,Int. J. Appl. Radiat. Isotopes, 33 /1982/ 937.
B. Johannsen, H. Spies, Chemie und Radiopharmakologie von Technetiumverbindungen, Akademie der Wiss. der DDR, Rossendorf 1981, p. 91.
R.G. Charles, H. Freiser,J. Org. Chemistry, 19 /1953/ 422.
G.R. Brubaker, J.C. Latta, D.C. Aquino,Inorg. Chem., 9 /1970/ 2608.
H. Spies, B. JohannsenInorg. Chim. Acta., 48 /1981/ 255.
S. Seifert, R. Münze, B. Johannsen,Radiochem. Radioanal. Lett., 54 /1982/ 153.
E. Bayer, E. Breitmaier,Chem. Ber., 101 /1968/ 1579.
G. Bandoli, U. Mazzi, D.A. Clemente, E. Roncari,J. Chem. Soc., Dalton Trans., /1982/ 2455.
B. Johannsen, H. Spies, Chemie und Radiopharmakologie von Technetiumverbindungen, Akademie der Wiss. der DDR, Rossendorf 1981, p. 151.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Spies, H., Pietzsch, H.J. & Abram, U. Lipophilic technetium complexes. Technetium chelates of some O, N, S donor Schiff bases. Journal of Radioanalytical and Nuclear Chemistry Letters 85, 339–344 (1984). https://doi.org/10.1007/BF02164057
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02164057