Skip to main content
SpringerLink
Log in

Solid state photodecomposition of alkaline earth tris/malonato/ferrates/III/

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

Solid state photolysis of alkaline earth tris/malonato/ferrates/III/, i.e., M3[Fe(CH2C2O4)3]2.xH2O /M=Mg, Ca, Sr, Ba/ has been investigated employing Mössbauer, infrared and reflectance spectroscopic techniques. The complexes were irradiated for 400 h using a medium pressure mercury vapour lamp of 250 Watts. Photoreduction led to the formation of M[FeII(CH2C2O4)2(H2O)2]. The extent of photoreduction showed the following order: Ca>Sr>Mg>Ba. The results have been compared with those of analogous alkaline earth tris/oxalato/ferrates/III/.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A.S. Brar, B.S. Randhawa,Bull. Chem. Soc. Japan, 54 /1981/ 3166.

    Google Scholar 

  2. A.S. Brar, B.S. Randhawa,Radiochem. Radioanal. Lett., 47 /1981/ 219.

    Google Scholar 

  3. B.S. Randhawa, A.S. Brar, T.K. Bansal,Radiochem. Radioanal. Lett., 53 /1982/ 359.

    Google Scholar 

  4. A.S. Brar, B.S. Randhawa,Polyhedron, 3 /1984/ 169.

    Google Scholar 

  5. A.S. Brar, S. Brar, S.S. Sandhu,Polyhedron, 2 /1983/ 421.

    Google Scholar 

  6. A.I. Vogel, A textbook of Quantitative Inorganic Analysis, including Elementary Instrumental Analysis, Eng. Language Book Soc. and Longman, London, 1973, p. 786.

    Google Scholar 

  7. B.S. Randhawa, Anandpal Singh,J. Radioanal. Nucl. Chem., Lett., 127 /1988/ 87.

    Google Scholar 

  8. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, 2nd Ed., J. Wiley and Sons, New York, 1970, p. 221.

    Google Scholar 

  9. M. Blume,Phys. Rev. Lett., 14 /1965/ 96.

    Google Scholar 

  10. A. Vértes, L. Korecz, K. Burger, Mössbauer Spectroscopy, Elsevier Sci. Publ. Co., New York, 1979, p. 47.

    Google Scholar 

  11. K. Kuraishi, T. Takano, K. Nagase, N. Tanaka,J. Inorg. Nucl. Chem., 43 /1981/ 2293.

    Google Scholar 

  12. W.W. Wendlandt, E.L. Simmons,J. Inorg. Nucl. Chem., 28 /1966/ 2420.

    Google Scholar 

  13. F.A. Cotton, G. Wilkinson, Advanced Inorganic Chemistry, 4th Ed., J. Wiley and Sons, New York, 1980, p. 272.

    Google Scholar 

  14. A.K. Galwey, M.A. Mohammed,J. Chem. Soc., Faraday Trans. I, 81 /1985/ 2503.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Guru Nanak Dev University, 143 005, Amritsar, India

    B. S. Randhawa, P. S. Bassi, Sukhraj K. Randhawa & Sandeep Kaur

Authors
  1. B. S. Randhawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. S. Bassi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sukhraj K. Randhawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Sandeep Kaur
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Randhawa, B.S., Bassi, P.S., Randhawa, S.K. et al. Solid state photodecomposition of alkaline earth tris/malonato/ferrates/III/. Journal of Radioanalytical and Nuclear Chemistry Letters 145, 249–257 (1990). https://doi.org/10.1007/BF02163414

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02163414

Keywords

Search

Navigation