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Analysis of the reactivity of materials having two different kinds of functional groups using the A″-McKay plot method

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Abstract

The hydrogen-isotope exchange reaction between HTO vapor (as a gaseous material) andp-aminophenol (or α-alanine) (as a solid material) having two different kinds of functional groups, has been studied to reveal the reactivity of the compounds. The reaction has been analyzed by the A″-McKay plot method and the rate constants (k) for each group have been obtained. Comparison ofk leads to the following: (1) the effect of the NH2 group inp-aminophenol on the reactivity is greater than that in α-alanine, and (2) the reactivity of compounds having two different kinds of functional groups can be analyzed by the A″-McKay plot method only.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Faculty of Engineering, Niigata University, 950-21, Ikarashi, Niigata, Japan

    H. Imaizumi & Y. Yumoto

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  1. H. Imaizumi
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  2. Y. Yumoto
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Imaizumi, H., Yumoto, Y. Analysis of the reactivity of materials having two different kinds of functional groups using the A″-McKay plot method. Journal of Radioanalytical and Nuclear Chemistry Letters 212, 399–408 (1996). https://doi.org/10.1007/BF02163285

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  • DOI: https://doi.org/10.1007/BF02163285

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